Enzyme-Catalyzed Synthesis of Aliphatic–Aromatic Oligoamides

Enzymatically catalyzed polycondensation of p-xylylenediamine and diethyl sebacate resulted in oligo(p-xylylene sebacamide) with high melting temperatures (223–230 °C) and the enzymatic polycondensation of dimethyl terephthalate and 1,8-diaminooctane leads to oligo(octamethylene terephthalamide) wit...

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Bibliographic Details
Published in:	Biomacromolecules Vol. 14; no. 5; pp. 1600 - 1606
Main Authors:	Stavila, E, Alberda van Ekenstein, G. O. R, Loos, K
Format:	Journal Article
Language:	English
Published:	Washington, DC American Chemical Society 13-05-2013
Subjects:	Applied sciences Biocatalysis Carboxylic Ester Hydrolases - chemistry Carboxylic Ester Hydrolases - isolation & purification Decanoic Acids - chemistry Diamines - chemistry Enzymes, Immobilized - chemistry Enzymes, Immobilized - isolation & purification Exact sciences and technology Fungal Proteins - chemistry Fungal Proteins - isolation & purification Fusarium - chemistry Fusarium - enzymology Hot Temperature Isoenzymes - chemistry Isoenzymes - isolation & purification Nylons - chemical synthesis Organic polymers Phthalic Acids - chemistry Physicochemistry of polymers Polycondensation Preparation, kinetics, thermodynamics, mechanism and catalysts Xylenes - chemistry Catalytic reaction Nylon Solution polycondensation Enzyme Triacylglycerol lipase Enzymatic catalysis Esterases Experimental study Oligomer Carboxylic ester hydrolases Hydrolases Catalyst activity Immobilized enzyme
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