Non-Symmetrically Substituted 1,1‘-Binaphthyls in Enantioselective Catalysis
Axial chirality was predicted by van't Hoff in his historical paper, which laid the foundations of stereochemistry. BINOL (1), one of the best known representatives of axially chiral molecules, was first prepared as a racemate in 1873, and later as an optically active compound, whose absolute c...
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| Published in: | Chemical reviews Vol. 103; no. 8; pp. 3213 - 3246 |
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| Main Authors: | , , |
| Format: | Journal Article |
| Language: | English |
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United States
American Chemical Society
01-08-2003
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| Abstract | Axial chirality was predicted by van't Hoff in his historical paper, which laid the foundations of stereochemistry. BINOL (1), one of the best known representatives of axially chiral molecules, was first prepared as a racemate in 1873, and later as an optically active compound, whose absolute configuration was determined in 1971. In 1979, Noyor showed BINOL (1) to be a superb chiral ligand in the stoichiometric reduction of ketones with LiA1H4, giving corresponding alcohols in less than or equal to 99% ee. |
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| AbstractList | Axial chirality was predicted by van't Hoff in his historical paper, which laid the foundations of stereochemistry. BINOL (1), one of the best known representatives of axially chiral molecules, was first prepared as a racemate in 1873, and later as an optically active compound, whose absolute configuration was determined in 1971. In 1979, Noyor showed BINOL (1) to be a superb chiral ligand in the stoichiometric reduction of ketones with LiA1H4, giving corresponding alcohols in less than or equal to 99% ee. |
| Author | Vyskočil, Štěpán Kočovský, Pavel Smrčina, Martin |
| Author_xml | – sequence: 1 givenname: Pavel surname: Kocovsky fullname: Kocovsky, Pavel – sequence: 2 givenname: Stepan surname: Vyskocil fullname: Vyskocil, Stepan – sequence: 3 givenname: Martin surname: Smrcina fullname: Smrcina, Martin |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/12914496$$D View this record in MEDLINE/PubMed |
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| CODEN | CHREAY |
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| Snippet | Axial chirality was predicted by van't Hoff in his historical paper, which laid the foundations of stereochemistry. BINOL (1), one of the best known... |
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| Title | Non-Symmetrically Substituted 1,1‘-Binaphthyls in Enantioselective Catalysis |
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