Densities and refractive indices of ethane and ethylene at astrophysically relevant temperatures

• Published in: Icarus (New York, N.Y. 1962) Vol. 296; pp. 179 - 182
• Main Authors: Satorre, M.Á., Millán, C., Molpeceres, G., Luna, R., Maté, B., Domingo, M., Escribano, R., Santonja, C.
• Format: Journal Article
• Language: English
• Published: Elsevier Inc 01-11-2017
• Subjects: Experimental techniques; Ices; IR spectroscopy; mechanical properties; Organic chemistry; Trans-Neptunian objects; Organic chemistry; Experimental techniques; Ices; IR spectroscopy; mechanical properties; Trans-Neptunian objects
• ISSN: 0019-1035; 1090-2643
• DOI: 10.1016/j.icarus.2017.05.005

•C2H6 and C2H4, products of methane radiation, are found in outer Solar System objects.•We have obtained for both molecules n and ρ from 13 to 65  K.•n and ρ raise with temperature of deposition up to a plateau.•Results confirm ice structure suggested by other experimental techniques.
We report the density and refractive index, at 633  nm, of ethane and ethylene ices at temperatures from 13 to 65 K, measured by double laser interferometry and a cryogenic quartz crystal microbalance in a high vacuum chamber. Both quantities rise with the temperature of deposition from 13 K up to a plateau, 40 K for ethane and 22 K for ethylene. An amorphous structure is suggested for temperatures below 40 K for ethane and below 20 K for ethylene. Above these temperatures, 40 K for ethane and 20 K for ethylene, a crystalline structure is proposed. Ethylene results deviate from linear growth between 25 and 35 K, where a metastable structure is reported in the literature. Density values increase from about 0.40 to 0.60 g cm−3 for ethane and from about 0.45 to almost 0.65 g cm−3 for ethylene. The real part of the refractive index changes from about 1.27 to 1.45 for ethane and from about 1.30 to almost 1.48 for ethylene. Results are relevant especially to the outer Solar System, where the presence of these molecules is reported, and for experiments involving them.