Simple, Efficient Catalyst System for the Palladium-Catalyzed Amination of Aryl Chlorides, Bromides, and Triflates

Palladium complexes supported by (o-biphenyl)P(t-Bu)2 (3) or (o-biphenyl)PCy2 (4) are efficient catalysts for the catalytic amination of a wide variety of aryl halides and triflates. Use of ligand 3 allows for the room-temperature catalytic amination of many aryl chloride, bromide, and triflate subs...

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Bibliographic Details
Published in:	Journal of organic chemistry Vol. 65; no. 4; pp. 1158 - 1174
Main Authors:	Wolfe, John P, Tomori, Hiroshi, Sadighi, Joseph P, Yin, Jingjun, Buchwald, Stephen L
Format:	Journal Article
Language:	English
Published:	United States American Chemical Society 25-02-2000
Subjects:	Amines - chemistry Amines - metabolism Aniline Compounds - chemistry Aniline Compounds - metabolism Biphenyl Compounds - chemistry Biphenyl Compounds - metabolism Bromobenzenes - chemistry Bromobenzenes - metabolism Catalysis Chlorobenzenes - chemistry Chlorobenzenes - metabolism Kinetics Magnetic Resonance Spectroscopy Models, Molecular Palladium - chemistry Palladium - metabolism Temperature
Online Access:	Get full text
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