Synchrotron-Based Micro-CT Investigation of Oxic Corrosion of Copper-Coated Carbon Steel for Potential Use in a Deep Geological Repository for Used Nuclear Fuel

• Published in: Geosciences (Basel) Vol. 8; no. 10; p. 360
• Main Authors: Standish, Thalia, Zagidulin, Dmitrij, Ramamurthy, Sridhar, Keech, Peter, Shoesmith, David, Noël, James
• Format: Journal Article
• Language: English
• Published: Basel MDPI AG 01-10-2018; MDPI
• Subjects: Carbon steel; Carbon steels; Coatings; Cold; cold spray; Cold treatment; Computed tomography; Computer simulation; Containers; Copper; Corrosion; Corrosion prevention; Damage; Defects; Dissolved oxygen; Earth science; Electrochemistry; electrodeposition; galvanic corrosion; Geology; Heat treatment; micro-CT; Nuclear fuels; nuclear waste management; Protective coatings; Sodium chloride; Spent nuclear fuels; Spray deposition; Stainless steel; Steel; Substrates; Synchrotron radiation; Tomography; X-ray tomography; Canada
• ISSN: 2076-3263; 2076-3263
• DOI: 10.3390/geosciences8100360

Within the multi-barrier system proposed for the permanent disposal of used nuclear fuel, the primary engineered barrier is the sealed metallic container. The present Canadian container design utilizes a carbon steel vessel coated with Cu for corrosion protection. In the event of a defect in the Cu coating that exposes the steel substrate, galvanically accelerated corrosion of steel is, in principle, possible. In this work, the progression of corrosion at a simulated through-coating defect in 3.0 mol/L NaCl solution containing dissolved O2 was monitored using electrochemical measurements and imaged non-destructively using synchrotron X-ray micro computed tomography (micro-CT). The damage volume at the base of the simulated defect was measured from the 3D micro-CT data and used to calculate the amount of O2 used to drive steel corrosion. The results demonstrate that the availability of O2 determines the rate and overall extent of corrosion, while the coatings produced using different deposition and treatment methods (cold spray deposition, heat-treated cold spray deposition, electrodeposition) lead to different corrosion propagation geometries, with the distribution of damage depending on the quality of the Cu/steel interface.