Formation Pathways of Mono- to Octa-Chlorinated Dibenzo‑p‑dioxins and Dibenzofurans in Main Organochemical Industries
The concentrations and formation pathways of mono- to octa-chlorinated dibenzo-p-dioxins (PCDDs) and dibenzofurans (PCDFs) were investigated in main organochemical industries. High levels of PCDDs and PCDFs were detected. The total concentrations of 27 PCDD/F congeners in chloranil, 2,4-D, and 1,4-d...
Saved in:
| Published in: | Environmental science & technology Vol. 49; no. 18; pp. 10945 - 10950 |
|---|---|
| Main Authors: | , , , , , , , , , |
| Format: | Journal Article |
| Language: | English |
| Published: |
United States
American Chemical Society
15-09-2015
|
| Subjects: | |
| Online Access: | Get full text |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| Abstract | The concentrations and formation pathways of mono- to octa-chlorinated dibenzo-p-dioxins (PCDDs) and dibenzofurans (PCDFs) were investigated in main organochemical industries. High levels of PCDDs and PCDFs were detected. The total concentrations of 27 PCDD/F congeners in chloranil, 2,4-D, and 1,4-dichlorobenzene were 5302397 ± 8944449, 20963 ± 15908, and 242 ± 67 pg g–1, respectively, and the less-chlorinated PCDD/F levels were 12006 ± 20155, 9536 ± 5594, and 195 ± 94 pg g–1, respectively. The distribution trends of less and more chlorinated PCDD/Fs were similar in different chemical plants because of their similar formation pathways, which may also be related to the degree of chlorination of chemical products and purification processes. 1,2,3,4-TeCDF and 2,4,8-TrCDF were selected as model molecules to calculate the bond dissociation energy, showing that 2-MCDF, 3-MCDF, and 2,8-DCDF are more easily formatted as shown by the analytical results. The formation pathways of less to more chlorinated PCDFs are proposed to explain why 2-MoCDF, 2,8-DiCDF, 2,4,8-TrCDF, and 2,3,4,7,8-PeCDF are the dominant congeners and to explain why 2,3,4,7,8-PeCDF is the largest contributor of I-TEQs in most studies. |
|---|---|
| AbstractList | The concentrations and formation pathways of mono- to octa-chlorinated dibenzo-p-dioxins (PCDDs) and dibenzofurans (PCDFs) were investigated in main organochemical industries. High levels of PCDDs and PCDFs were detected. The total concentrations of 27 PCDD/F congeners in chloranil, 2,4-D, and 1,4-dichlorobenzene were 5302397 ± 8944449, 20963 ± 15908, and 242 ± 67 pg g(-1), respectively, and the less-chlorinated PCDD/F levels were 12006 ± 20155, 9536 ± 5594, and 195 ± 94 pg g(-1), respectively. The distribution trends of less and more chlorinated PCDD/Fs were similar in different chemical plants because of their similar formation pathways, which may also be related to the degree of chlorination of chemical products and purification processes. 1,2,3,4-TeCDF and 2,4,8-TrCDF were selected as model molecules to calculate the bond dissociation energy, showing that 2-MCDF, 3-MCDF, and 2,8-DCDF are more easily formatted as shown by the analytical results. The formation pathways of less to more chlorinated PCDFs are proposed to explain why 2-MoCDF, 2,8-DiCDF, 2,4,8-TrCDF, and 2,3,4,7,8-PeCDF are the dominant congeners and to explain why 2,3,4,7,8-PeCDF is the largest contributor of I-TEQs in most studies. The concentrations and formation pathways of mono- to octa-chlorinated dibenzo-p-dioxins (PCDDs) and dibenzofurans (PCDFs) were investigated in main organochemical industries. High levels of PCDDs and PCDFs were detected. The total concentrations of 27 PCDD/F congeners in chloranil, 2,4-D, and 1,4-dichlorobenzene were 5302397 plus or minus 8944449, 20963 plus or minus 15908, and 242 plus or minus 67 pg g..., respectively, and the less-chlorinated PCDD/F levels were 12006 plus or minus 20155, 9536 plus or minus 5594, and 195 plus or minus 94 pg g..., respectively. The distribution trends of less and more chlorinated PCDD/Fs were similar in different chemical plants because of their similar formation pathways, which may also be related to the degree of chlorination of chemical products and purification processes. 1,2,3,4-TeCDF and 2,4,8-TrCDF were selected as model molecules to calculate the bond dissociation energy, showing that 2-MCDF, 3-MCDF, and 2,8-DCDF are more easily formatted as shown by the analytical results. The formation pathways of less to more chlorinated PCDFs are proposed to explain why 2-MoCDF, 2,8-DiCDF, 2,4,8-TrCDF, and 2,3,4,7,8-PeCDF are the dominant congeners and to explain why 2,3,4,7,8-PeCDF is the largest contributor of I-TEQs in most studies. (ProQuest: ... denotes formulae/symbols omitted.) The concentrations and formation pathways of mono- to octa-chlorinated dibenzo-p-dioxins (PCDDs) and dibenzofurans (PCDFs) were investigated in main organochemical industries. High levels of PCDDs and PCDFs were detected. The total concentrations of 27 PCDD/F congeners in chloranil, 2,4-D, and 1,4-dichlorobenzene were 5302397 ± 8944449, 20963 ± 15908, and 242 ± 67 pg g..., respectively, and the less-chlorinated PCDD/F levels were 12006 ± 20155, 9536 ± 5594, and 195 ± 94 pg g..., respectively. The distribution trends of less and more chlorinated PCDD/Fs were similar in different chemical plants because of their similar formation pathways, which may also be related to the degree of chlorination of chemical products and purification processes. 1,2,3,4-TeCDF and 2,4,8-TrCDF were selected as model molecules to calculate the bond dissociation energy, showing that 2-MCDF, 3-MCDF, and 2,8-DCDF are more easily formatted as shown by the analytical results. The formation pathways of less to more chlorinated PCDFs are proposed to explain why 2-MoCDF, 2,8-DiCDF, 2,4,8-TrCDF, and 2,3,4,7,8-PeCDF are the dominant congeners and to explain why 2,3,4,7,8-PeCDF is the largest contributor of I-TEQs in most studies. (ProQuest: ... denotes formulae/symbols omitted.) |
| Author | Han, Ying Tian, Zhenyu Liao, Xiao Wang, Pu Chen, Xuebin Liu, Wenbin Zhao, Yuyang Wang, Mengjing Zheng, Minghui Pan, Wenxiao |
| AuthorAffiliation | State Key Laboratory of Environmental Chemistry and Ecotoxicology Research Center for Eco-Environmental Sciences |
| AuthorAffiliation_xml | – name: Research Center for Eco-Environmental Sciences – name: State Key Laboratory of Environmental Chemistry and Ecotoxicology |
| Author_xml | – sequence: 1 givenname: Ying surname: Han fullname: Han, Ying – sequence: 2 givenname: Wenbin surname: Liu fullname: Liu, Wenbin email: liuwb@rcees.ac.cn – sequence: 3 givenname: Wenxiao surname: Pan fullname: Pan, Wenxiao – sequence: 4 givenname: Pu surname: Wang fullname: Wang, Pu – sequence: 5 givenname: Zhenyu surname: Tian fullname: Tian, Zhenyu – sequence: 6 givenname: Yuyang surname: Zhao fullname: Zhao, Yuyang – sequence: 7 givenname: Mengjing surname: Wang fullname: Wang, Mengjing – sequence: 8 givenname: Xuebin surname: Chen fullname: Chen, Xuebin – sequence: 9 givenname: Xiao surname: Liao fullname: Liao, Xiao – sequence: 10 givenname: Minghui surname: Zheng fullname: Zheng, Minghui |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/26301518$$D View this record in MEDLINE/PubMed |
| BookMark | eNp1kcFqGzEQhkVISZy059yKIJdCWWdmZe3Kx-A2aSDBOaTQ2zKWpVhhV3KlXVr31FfoK_ZJImM3hUIPGoH0_f9o9J-wQx-8YewMYYxQ4gXpNDapH8sFlJUSB2yEsoRCKomHbASAopiK6ssxO0npCQBKAeqIHZeVAJSoRmxzFWJHvQue31O_-kabxIPld8GHgveBz3VPxWzVhug89WbJP7iF8T_C75-_1nktXfjufOLkX27sECmfOM_vKJd5fCQf9Mp0TlPLb_xySH10Jr1mryy1ybzZ76fs89XHh9mn4nZ-fTO7vC1oImRflAql0XoiFFkN01oCTFDUoIQEshZkVclKTWRdQ5VHFdYKQqMU2jyryR6n7N3Odx3D1yF_VtO5pE3bkjdhSA3WZYm1VNMqo-f_oE9hiD6_LlMopwpzydTFjtIxpBSNbdbRdRQ3DUKzTaXJqTRb9T6VrHi79x0WnVm-8H9iyMD7HbBV_u35H7tnnN-a8w |
| CODEN | ESTHAG |
| CitedBy_id | crossref_primary_10_1021_acs_est_7b04848 crossref_primary_10_1016_j_scitotenv_2018_08_279 crossref_primary_10_3390_ijerph16071267 crossref_primary_10_1016_j_chemosphere_2016_07_011 crossref_primary_10_1016_j_chemosphere_2022_134995 crossref_primary_10_1016_j_jece_2023_109665 crossref_primary_10_1016_j_jallcom_2016_04_100 crossref_primary_10_1016_j_tetlet_2016_06_100 crossref_primary_10_1021_acs_est_5b06095 crossref_primary_10_1016_j_jhazmat_2021_126265 crossref_primary_10_1016_j_jhazmat_2021_127673 crossref_primary_10_1088_1755_1315_208_1_012097 crossref_primary_10_1016_j_chemosphere_2016_04_110 crossref_primary_10_1021_acs_est_2c07322 |
| Cites_doi | 10.1021/es503110j 10.1021/es0485513 10.1021/es402136s 10.1016/j.chemosphere.2011.08.020 10.1016/j.chemosphere.2014.11.039 10.1016/j.chroma.2014.12.013 10.1016/j.chemosphere.2014.05.010 10.1016/j.chemosphere.2013.11.068 10.1021/ar020104+ 10.1016/j.scitotenv.2014.01.113 10.1016/j.aca.2012.04.004 10.1016/j.chemosphere.2013.03.031 10.1016/j.pecs.2008.12.001 10.1016/j.cej.2015.05.015 10.1016/j.envres.2005.12.003 10.1016/j.chemosphere.2010.02.039 10.1016/j.envpol.2011.11.015 10.1016/j.chemosphere.2006.09.057 10.1021/es5023619 10.1016/j.chemosphere.2007.07.042 10.1016/j.chemosphere.2015.02.005 10.1021/es404926g 10.1016/j.scitotenv.2013.07.130 10.1016/j.jhazmat.2009.02.068 10.1016/j.chemosphere.2013.12.065 10.1016/j.chemosphere.2011.09.034 10.1016/S1001-0742(11)60752-3 10.1016/j.chemosphere.2004.09.024 10.1016/j.chemosphere.2009.01.075 |
| ContentType | Journal Article |
| Copyright | Copyright © 2015 American Chemical
Society Copyright American Chemical Society Sep 15, 2015 |
| Copyright_xml | – notice: Copyright © 2015 American Chemical Society – notice: Copyright American Chemical Society Sep 15, 2015 |
| DBID | CGR CUY CVF ECM EIF NPM AAYXX CITATION 7QO 7ST 7T7 7U7 8FD C1K FR3 P64 SOI 7TV |
| DOI | 10.1021/acs.est.5b02683 |
| DatabaseName | Medline MEDLINE MEDLINE (Ovid) MEDLINE MEDLINE PubMed CrossRef Biotechnology Research Abstracts Environment Abstracts Industrial and Applied Microbiology Abstracts (Microbiology A) Toxicology Abstracts Technology Research Database Environmental Sciences and Pollution Management Engineering Research Database Biotechnology and BioEngineering Abstracts Environment Abstracts Pollution Abstracts |
| DatabaseTitle | MEDLINE Medline Complete MEDLINE with Full Text PubMed MEDLINE (Ovid) CrossRef Biotechnology Research Abstracts Technology Research Database Toxicology Abstracts Engineering Research Database Industrial and Applied Microbiology Abstracts (Microbiology A) Environment Abstracts Biotechnology and BioEngineering Abstracts Environmental Sciences and Pollution Management Pollution Abstracts |
| DatabaseTitleList | MEDLINE Pollution Abstracts Biotechnology Research Abstracts |
| Database_xml | – sequence: 1 dbid: ECM name: MEDLINE url: https://search.ebscohost.com/login.aspx?direct=true&db=cmedm&site=ehost-live sourceTypes: Index Database |
| DeliveryMethod | fulltext_linktorsrc |
| Discipline | Engineering Environmental Sciences |
| EISSN | 1520-5851 |
| EndPage | 10950 |
| ExternalDocumentID | 3816539891 10_1021_acs_est_5b02683 26301518 a19995614 |
| Genre | Research Support, Non-U.S. Gov't Journal Article Feature |
| GroupedDBID | - .K2 1AW 3R3 4R4 53G 55A 5GY 5VS 63O 7~N 85S AABXI ABFLS ABMVS ABOGM ABPPZ ABPTK ABUCX ABUFD ACGFS ACGOD ACIWK ACJ ACPRK ACS AEESW AENEX AFEFF AFRAH ALMA_UNASSIGNED_HOLDINGS AQSVZ BAANH BKOMP CS3 DZ EBS ED ED~ EJD F5P GNL IH9 JG JG~ K2 LG6 MS PQEST PQQKQ ROL RXW TN5 TWZ U5U UHB UI2 UKR UPT VF5 VG9 VQA W1F WH7 X XFK XZL YZZ --- -DZ -~X ..I .DC 4.4 6TJ AAHBH ABJNI ABQRX ADHLV ADUKH AGXLV AHGAQ CGR CUPRZ CUY CVF ECM EIF GGK MS~ MW2 NPM XSW ZCA AAYXX CITATION 7QO 7ST 7T7 7U7 8FD C1K FR3 P64 SOI 7TV |
| ID | FETCH-LOGICAL-a435t-2815ecc438afc097500413708350aff05665684577069363ff3a1e881f230ea43 |
| IEDL.DBID | ACS |
| ISSN | 0013-936X |
| IngestDate | Fri Aug 16 23:10:51 EDT 2024 Thu Oct 10 17:59:17 EDT 2024 Fri Aug 23 00:37:48 EDT 2024 Sat Sep 28 08:05:28 EDT 2024 Thu Aug 27 13:42:37 EDT 2020 |
| IsDoiOpenAccess | false |
| IsOpenAccess | true |
| IsPeerReviewed | true |
| IsScholarly | true |
| Issue | 18 |
| Language | English |
| LinkModel | DirectLink |
| MergedId | FETCHMERGED-LOGICAL-a435t-2815ecc438afc097500413708350aff05665684577069363ff3a1e881f230ea43 |
| Notes | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
| OpenAccessLink | https://ir.rcees.ac.cn/bitstream/311016/32581/1/Formation%20Pathways%20of%20Mono-%20to%20Octa-Chlorinated%20Dibenzo-p-dioxins%20and%20Dibenzofurans%20in%20Main%20Organochemical%20Industries.pdf |
| PMID | 26301518 |
| PQID | 1715981159 |
| PQPubID | 45412 |
| PageCount | 6 |
| ParticipantIDs | proquest_miscellaneous_1722175896 proquest_journals_1715981159 crossref_primary_10_1021_acs_est_5b02683 pubmed_primary_26301518 acs_journals_10_1021_acs_est_5b02683 |
| ProviderPackageCode | JG~ 55A AABXI GNL VF5 7~N ACJ VG9 W1F ACS AEESW AFEFF .K2 ABMVS ABUCX IH9 BAANH AQSVZ ED~ UI2 |
| PublicationCentury | 2000 |
| PublicationDate | 2015-09-15 |
| PublicationDateYYYYMMDD | 2015-09-15 |
| PublicationDate_xml | – month: 09 year: 2015 text: 2015-09-15 day: 15 |
| PublicationDecade | 2010 |
| PublicationPlace | United States |
| PublicationPlace_xml | – name: United States – name: Easton |
| PublicationTitle | Environmental science & technology |
| PublicationTitleAlternate | Environ. Sci. Technol |
| PublicationYear | 2015 |
| Publisher | American Chemical Society |
| Publisher_xml | – name: American Chemical Society |
| References | ref9/cit9 ref6/cit6 ref3/cit3 ref27/cit27 ref18/cit18 ref11/cit11 ref25/cit25 ref16/cit16 ref29/cit29 ref23/cit23 ref14/cit14 ref8/cit8 ref5/cit5 ref2/cit2 ref28/cit28 ref20/cit20 ref17/cit17 ref10/cit10 ref26/cit26 ref19/cit19 ref21/cit21 ref12/cit12 ref15/cit15 ref22/cit22 ref13/cit13 ref4/cit4 ref1/cit1 ref24/cit24 ref7/cit7 |
| References_xml | – ident: ref24/cit24 doi: 10.1021/es503110j – ident: ref7/cit7 doi: 10.1021/es0485513 – ident: ref2/cit2 doi: 10.1021/es402136s – ident: ref27/cit27 doi: 10.1016/j.chemosphere.2011.08.020 – ident: ref10/cit10 doi: 10.1016/j.chemosphere.2014.11.039 – ident: ref25/cit25 doi: 10.1016/j.chroma.2014.12.013 – ident: ref16/cit16 doi: 10.1016/j.chemosphere.2014.05.010 – ident: ref21/cit21 doi: 10.1016/j.chemosphere.2013.11.068 – ident: ref26/cit26 doi: 10.1021/ar020104+ – ident: ref1/cit1 doi: 10.1016/j.scitotenv.2014.01.113 – ident: ref5/cit5 doi: 10.1016/j.aca.2012.04.004 – ident: ref13/cit13 doi: 10.1016/j.chemosphere.2013.03.031 – ident: ref28/cit28 doi: 10.1016/j.pecs.2008.12.001 – ident: ref20/cit20 doi: 10.1016/j.cej.2015.05.015 – ident: ref18/cit18 doi: 10.1016/j.envres.2005.12.003 – ident: ref8/cit8 doi: 10.1016/j.chemosphere.2010.02.039 – ident: ref4/cit4 doi: 10.1016/j.envpol.2011.11.015 – ident: ref6/cit6 doi: 10.1016/j.chemosphere.2006.09.057 – ident: ref9/cit9 doi: 10.1021/es5023619 – ident: ref19/cit19 doi: 10.1016/j.chemosphere.2007.07.042 – ident: ref3/cit3 doi: 10.1016/j.chemosphere.2015.02.005 – ident: ref15/cit15 doi: 10.1021/es404926g – ident: ref11/cit11 doi: 10.1016/j.scitotenv.2013.07.130 – ident: ref29/cit29 doi: 10.1016/j.jhazmat.2009.02.068 – ident: ref17/cit17 doi: 10.1016/j.chemosphere.2013.12.065 – ident: ref12/cit12 doi: 10.1016/j.chemosphere.2011.09.034 – ident: ref22/cit22 doi: 10.1016/S1001-0742(11)60752-3 – ident: ref14/cit14 doi: 10.1016/j.chemosphere.2004.09.024 – ident: ref23/cit23 doi: 10.1016/j.chemosphere.2009.01.075 |
| SSID | ssj0002308 |
| Score | 2.3108335 |
| Snippet | The concentrations and formation pathways of mono- to octa-chlorinated dibenzo-p-dioxins (PCDDs) and dibenzofurans (PCDFs) were investigated in main... |
| SourceID | proquest crossref pubmed acs |
| SourceType | Aggregation Database Index Database Publisher |
| StartPage | 10945 |
| SubjectTerms | Benzofurans - chemical synthesis Chemical plants Dioxins Halogenation Industry Molecules Organic chemistry PCB Polychlorinated biphenyls Polychlorinated Dibenzodioxins - analogs & derivatives Polychlorinated Dibenzodioxins - chemical synthesis Thermodynamics |
| Title | Formation Pathways of Mono- to Octa-Chlorinated Dibenzo‑p‑dioxins and Dibenzofurans in Main Organochemical Industries |
| URI | http://dx.doi.org/10.1021/acs.est.5b02683 https://www.ncbi.nlm.nih.gov/pubmed/26301518 https://www.proquest.com/docview/1715981159 https://search.proquest.com/docview/1722175896 |
| Volume | 49 |
| hasFullText | 1 |
| inHoldings | 1 |
| isFullTextHit | |
| isPrint | |
| link | http://sdu.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwlZ07T8MwEIBPPBYYeBQK4SUjMcDgksRx4oyotGLhIRUktshJbNElqUgrHhN_gb_IL-GcJgGEKsGQDLHlWD6f7zvZvgM4UlKkLvrJ1HMCRb1Ax1QmklFux7ZUQgmpzW3ki0FwdS_OeyZMzsmMHXzXOZVJ0cEFssNjdBcEm4dFN0BOMBTUHTSLLpK0qJMVhMy_b6L4_GrAmKGk-GmGZrBlaWP6q__o3RqsVCBJzqaSX4c5lbVg-Vt4wRa0e1-32LBqpcbFBrz06yuL5AYJ8Em-FCTXBPU7p2Sck-tkLGn3oTychyyakvNhrLLX_OPtfYRPOsyfh1lBZNaU6ImxeWSYkUuJr_KGp8nFVQYjIHV-EFVswl2_d9u9oFUOBioRpMbUFQ5HKXsMhZbYIfKFjWYvMOBmS60RnxAIhceDwPZx3JnWTDpKCEejRBS20YaFLM_UNhDj2bmp0lLx1AtZKFNbK-MfxZ5gMUssOMLRjCodKqJye9x1IvMRhziqhtiC41py0WgakWN21b1ast-aDZDgBIJwaMFhU4xKZXZKZKbyianjoqvGRehbsDWdEc2_XB_XRO6Inb91dxeWkLG4OWLi8D1YGD9O1D7MF-nkoJzBn6NL7jw |
| link.rule.ids | 315,782,786,2769,27085,27933,27934,56747,56797 |
| linkProvider | American Chemical Society |
| linkToHtml | http://sdu.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwlV3NTtwwEB7BcqA9FArdsmULRuLAxSWJ48Q5ov3RIn6KBEjcIiex1b0kq3pXsJz6CrwiT9JxNgmLKqRyiA-2NbFmPJ5vZM8MwKGSIvPQT6a-GyrqhzqhMpWMcidxpBJKSG2jkUfX4eWd6A9smhynjoXBRRikZMpL_JfsAu6x7cNz8gdP0GsQbBXWeIBQ2IKh3nVz9iKgFnXNgogFd00yn38IWGuUmtfW6A2IWZqa4cb7F7kJnypYSU4W--AzrKh8Cz4uJRvcgvbgJaYNp1ZKbbZhPqwDGMkV4sF7OTek0AS1vaBkWpCf6VTS3q_yqR4i04z0x4nKH4vnP08T_LJx8TDODZF5M6Jn1gKScU4uJDZlvKetzFWmJiB1tRBlvsDtcHDTG9GqIgOVCKum1BMuR5n7DEWYOhGiDQeNYGhhnCO1RjCF8FD4PAydANnPtGbSVUK4GgWjkEYbWnmRqx0g1s_zMqWl4pkfsUhmjlbWW0p8wRKWduAQuRlXGmXi8rLcc2PbiSyOKxZ34KgWYDxZ5Od4e2q3FvAS2RDxnEBYHHXgoBlGFbP3JjJXxczO8dBx4yIKOvB1sTGaf3kBnpDcFd_-b7n7sD66uTiPz08vz3bhA6Ivbh-fuLwLrenvmfoOqyab7ZWb-i_Fb_ap |
| linkToPdf | http://sdu.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV1LT9wwEB6VrYTgQFtgy7ZbaqQ9cDEkcZw4R7QPLeIpARK3yElsdS_JCu-Kx4m_wF_kl3ScTdKtKiTUQ3ywrcnI4_F8I3tmAHpKisxDP5n6bqioH-qEylQyyp3EkUooIbWNRh5fhee3YjC0aXL8OhYGmTBIyZSX-Farp5muMgy4h7Yfz8oDnqDnINgKfORBGFmX66h_1Zy_CKpFXbcgYsFtk9DnHwLWIqXmb4v0Bswszc3o0_8x-hk2KnhJjhb74Qt8UPkmrC8lHdyE9vBPbBtOrZTbbMHjqA5kJJeIC-_loyGFJqj1BSWzglykM0n7v8one4hQMzKYJCp_Kl6fX6b4ZZPiYZIbIvNmRM-tJSSTnJxJbMq4T1uhq0xRQOqqIcpsw81oeN0f06oyA5UIr2bUEy5H2fsMRZk6EaIOB41haOGcI7VGUIUwUfg8DJ0ARcC0ZtJVQrgahaOQRhtaeZGrHSDW3_MypaXimR-xSGaOVtZrSnzBEpZ2oIerGVeaZeLy0txzY9uJSxxXS9yB_VqI8XSRp-Ptqd1ayEtkQ8R1AuFx1IG9ZhhVzd6fyFwVczvHQweOiyjowNfF5mj-5QV4UnJXfHsfuz9h9XIwik-Pz0--wxqCMG7foLi8C63Z3Vz9gBWTzXfLff0bxbH5LA |
| openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Formation+Pathways+of+Mono-+to+Octa-Chlorinated+Dibenzo-p-dioxins+and+Dibenzofurans+in+Main+Organochemical+Industries&rft.jtitle=Environmental+science+%26+technology&rft.au=Han%2C+Ying&rft.au=Liu%2C+Wenbin&rft.au=Pan%2C+Wenxiao&rft.au=Wang%2C+Pu&rft.date=2015-09-15&rft.issn=0013-936X&rft.volume=49&rft.issue=18&rft.spage=10945&rft.epage=10945&rft_id=info:doi/10.1021%2Facs.est.5b02683&rft.externalDBID=NO_FULL_TEXT |
| thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=0013-936X&client=summon |
| thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=0013-936X&client=summon |
| thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=0013-936X&client=summon |