In Situ Neutron Reflectometry Study of Solid Electrolyte Interface (SEI) Formation on Tungsten Thin-Film Electrodes
Tungsten, a non-Li-intercalating material, was used as a platform to study solid–electrolyte interface/interphase (SEI) formation in lithium hexafluorphosphate in mixed diethyl carbonate (DEC)/ethylene carbonate electrolyte solutions using in situ neutron reflectometry (NR). A NR measurement determi...
Saved in:
| Published in: | ACS applied materials & interfaces Vol. 11; no. 50; pp. 47553 - 47563 |
|---|---|
| Main Authors: | , |
| Format: | Journal Article |
| Language: | English |
| Published: |
United States
American Chemical Society
18-12-2019
|
| Subjects: | |
| Online Access: | Get full text |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| Abstract | Tungsten, a non-Li-intercalating material, was used as a platform to study solid–electrolyte interface/interphase (SEI) formation in lithium hexafluorphosphate in mixed diethyl carbonate (DEC)/ethylene carbonate electrolyte solutions using in situ neutron reflectometry (NR). A NR measurement determines the neutron scattering length density (SLD)-depth profile, from which a composition-depth profile can be inferred. Isotopic labeling/contrast variation measurements were conducted using a series of three electrolyte solutions: one with both solvents deuterated, one with neither deuterated, and another with only DEC deuterated. A two-layer SEI formed upon polarization to +0.25 V vs Li/Li+. Insensitivity of the inner SEI layer to solvent deuteration suggested limited incorporation of hydrogen atoms from the solvent molecules. Its low SLD indicates that Li2O could be a major constituent. The outer SEI layer SLD scaled with that of the solution, indicating that it either had solution-filled porosity, incorporated hydrogen atoms from the solvent, or both. Returning the electrode to +2.65 V removed lithium from both surface layers, though the effect was more pronounced for the inner layer. Potential cycling had the effect of increasing the solution-derived species content in the inner SEI and decreased the contrast between the inner and outer layers, possibly indicating intermixing of the layers. |
|---|---|
| AbstractList | Tungsten, a non-Li-intercalating material, was used as a platform to study solid–electrolyte interface/interphase (SEI) formation in lithium hexafluorphosphate in mixed diethyl carbonate (DEC)/ethylene carbonate electrolyte solutions using in situ neutron reflectometry (NR). A NR measurement determines the neutron scattering length density (SLD)-depth profile, from which a composition-depth profile can be inferred. Isotopic labeling/contrast variation measurements were conducted using a series of three electrolyte solutions: one with both solvents deuterated, one with neither deuterated, and another with only DEC deuterated. A two-layer SEI formed upon polarization to +0.25 V vs Li/Li+. Insensitivity of the inner SEI layer to solvent deuteration suggested limited incorporation of hydrogen atoms from the solvent molecules. Its low SLD indicates that Li2O could be a major constituent. The outer SEI layer SLD scaled with that of the solution, indicating that it either had solution-filled porosity, incorporated hydrogen atoms from the solvent, or both. Returning the electrode to +2.65 V removed lithium from both surface layers, though the effect was more pronounced for the inner layer. Potential cycling had the effect of increasing the solution-derived species content in the inner SEI and decreased the contrast between the inner and outer layers, possibly indicating intermixing of the layers. Tungsten, a non-Li-intercalating material, was used as a platform to study solid-electrolyte interface/interphase (SEI) formation in lithium hexafluorphosphate in mixed diethyl carbonate (DEC)/ethylene carbonate (EC) electrolyte solutions using in situ neutron reflectometry (NR). A NR measurement determines the neutron scattering length density (SLD)-depth profile, from which a composition-depth profile can be inferred. Isotopic labelling/contrast variation measurements were conducted using a series of three electrolyte solutions: one with both solvents deuterated, one with neither deuterated, and another with only DEC deuterated. A two-layer SEI formed upon polarization to +0.25 V vs. Li/Li + . Insensitivity of the inner SEI layer to solvent deuteration suggested limited incorporation of hydrogen atoms from the solvent molecules. Its low SLD indicates Li 2 O could be a major constituent. The outer SEI layer SLD scaled with that of the solution, indicating it either had solution filled-porosity or incorporated hydrogen atoms from the solvent, or both. Returning the electrode to +2.65 V removed lithium from both surface layers, though the effect was more pronounced for the inner layer. Potential cycling had the effect of increasing the solution-derived species content in the inner SEI and decreased the contrast between the inner and outer layers, possibly indicating intermixing of the layers. Tungsten, a non-Li-intercalating material, was used as a platform to study solid-electrolyte interface/interphase (SEI) formation in lithium hexafluorphosphate in mixed diethyl carbonate (DEC)/ethylene carbonate electrolyte solutions using in situ neutron reflectometry (NR). A NR measurement determines the neutron scattering length density (SLD)-depth profile, from which a composition-depth profile can be inferred. Isotopic labeling/contrast variation measurements were conducted using a series of three electrolyte solutions: one with both solvents deuterated, one with neither deuterated, and another with only DEC deuterated. A two-layer SEI formed upon polarization to +0.25 V vs Li/Li . Insensitivity of the inner SEI layer to solvent deuteration suggested limited incorporation of hydrogen atoms from the solvent molecules. Its low SLD indicates that Li O could be a major constituent. The outer SEI layer SLD scaled with that of the solution, indicating that it either had solution-filled porosity, incorporated hydrogen atoms from the solvent, or both. Returning the electrode to +2.65 V removed lithium from both surface layers, though the effect was more pronounced for the inner layer. Potential cycling had the effect of increasing the solution-derived species content in the inner SEI and decreased the contrast between the inner and outer layers, possibly indicating intermixing of the layers. |
| Author | Dura, Joseph A Rus, Eric D |
| AuthorAffiliation | NIST Center for Neutron Research |
| AuthorAffiliation_xml | – name: NIST Center for Neutron Research |
| Author_xml | – sequence: 1 givenname: Eric D orcidid: 0000-0001-5031-6888 surname: Rus fullname: Rus, Eric D email: eric.rus@nist.gov – sequence: 2 givenname: Joseph A orcidid: 0000-0001-6877-959X surname: Dura fullname: Dura, Joseph A |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/31815415$$D View this record in MEDLINE/PubMed |
| BookMark | eNp1kc1r3DAQxUVJaT7aa49FxzTgjSRLtnQplLCbLoQGuulZyPI4UbClVJIL-99XYTdLcwgMzMD83huhd4qOfPCA0GdKFpQwemlsMpNbqI42QrF36IQqzivJBDs6zJwfo9OUHglpakbEB3RcU0kFp-IEpbXHG5dn_BPmHIPHv2AYweYwQY5bvMlzv8VhwJswuh4vn1cxjNsMeO0zxMFYwOeb5forXoU4meyKRam72d-nDGV4cL5auXF60faQPqL3gxkTfNr3M_R7tby7-lHd3F6vr77fVIYzkSsKTWOs5EowqVrFmDW0Jlz2wOkgrZUdVbK2jWhMpzqlWEtEyxkTRgqlQNZn6NvO92nuJugt-BzNqJ-im0zc6mCcfr3x7kHfh7-65S1pGCkG53uDGP7MkLKeXLIwjsZDmJNmNat5S5u6Kehih9oYUoowHM5Qop-T0ruk9D6pIvjy_-MO-Es0BbjYAUWoH8Mcffmrt9z-AY9FoJo |
| CitedBy_id | crossref_primary_10_1016_j_molliq_2022_119773 crossref_primary_10_1002_sstr_202300119 crossref_primary_10_1021_acsmaterialslett_3c00207 crossref_primary_10_1016_j_jechem_2022_07_007 crossref_primary_10_1002_smll_202107491 crossref_primary_10_1107_S1600576721011924 crossref_primary_10_1039_D1TA09639G crossref_primary_10_1039_D3MH00135K crossref_primary_10_1021_acs_chemrev_3c00826 crossref_primary_10_1134_S1063779622030030 crossref_primary_10_1063_1_5142643 crossref_primary_10_1134_S1027451021040285 crossref_primary_10_1063_5_0065860 crossref_primary_10_1039_D2TA04309B crossref_primary_10_1134_S1027451023040225 crossref_primary_10_1002_aenm_202102687 crossref_primary_10_1021_acsami_2c06471 crossref_primary_10_1021_acsami_2c16737 crossref_primary_10_1088_2053_1591_ace592 crossref_primary_10_1039_D1SC06181J crossref_primary_10_15407_ujpe68_4_259 crossref_primary_10_31857_S1028096023080046 crossref_primary_10_1016_j_nanoen_2024_109337 crossref_primary_10_1021_acs_chemrev_2c00002 |
| Cites_doi | 10.1039/C7EE02555F 10.1016/S0921-5093(00)00745-0 10.1107/S0365110X59000767 10.1016/j.jpowsour.2018.11.093 10.1016/0921-4526(94)90156-2 10.1016/j.apsusc.2017.01.290 10.5796/electrochemistry.78.413 10.1107/S0108768186098476 10.1039/C7CS00180K 10.1107/S0108768105003629 10.1016/S0022-0728(74)80377-3 10.1515/IJNSNS.2009.10.3.273 10.1149/1.1838420 10.1063/1.333738 10.1039/C0SM00558D 10.1080/10448639208218770 10.1063/1.4803699 10.1021/ic50035a033 10.1063/1.2219744 10.1021/cm3006887 10.1039/c3cp44438d 10.1021/cr500207g 10.1107/S0021889890003636 10.1039/C6CP00978F 10.1021/acsnano.6b02032 10.1006/jssc.1999.8173 10.1016/0040-6090(82)90147-X 10.1021/acs.jpclett.5b01727 10.1016/j.cocis.2011.11.001 10.1016/j.electacta.2010.05.072 10.1021/ac60156a007 10.1016/0022-4596(79)90199-3 10.1016/S0378-7753(01)00826-6 10.1021/jp047240b 10.1023/A:1010143904328 10.1039/c3cc49269a 10.1063/1.122442 10.1016/S0022-0728(72)80485-6 10.1016/j.joule.2018.12.013 10.1021/la402496z 10.1016/B978-0-444-63739-0.00005-0 10.1016/j.apsusc.2019.04.241 10.1016/j.actamat.2015.11.049 10.1021/la303837c 10.1021/acsami.7b09181 10.1088/1742-6596/502/1/012054 10.1088/0953-8984/3/26/001 10.1524/zkri.1979.150.1-4.133 10.1021/acsami.6b01170 10.1021/acs.jpcc.5b06817 10.1021/acs.jpcc.6b02523 10.1107/S1600576718011974 10.1039/C4SM00850B 10.1107/S0567739475000745 10.1107/S0567740869004146 10.1107/S0567739478001151 10.1021/am5032055 10.1149/2.1441707jes 10.1116/1.4936261 10.1088/0953-8984/10/33/002 10.1038/s41565-018-0284-y 10.1149/1.2123617 10.1021/cr030203g 10.1016/0025-5408(74)90120-2 10.1149/1.2128859 10.1021/acs.nanolett.6b02926 10.1149/1.1353568 10.1143/JJAP.35.L67 |
| ContentType | Journal Article |
| DBID | NPM AAYXX CITATION 7X8 5PM |
| DOI | 10.1021/acsami.9b16592 |
| DatabaseName | PubMed CrossRef MEDLINE - Academic PubMed Central (Full Participant titles) |
| DatabaseTitle | PubMed CrossRef MEDLINE - Academic |
| DatabaseTitleList | PubMed |
| DeliveryMethod | fulltext_linktorsrc |
| Discipline | Engineering |
| EISSN | 1944-8252 |
| EndPage | 47563 |
| ExternalDocumentID | 10_1021_acsami_9b16592 31815415 b112045229 |
| Genre | Journal Article |
| GrantInformation_xml | – fundername: Intramural NIST DOC grantid: 9999-NIST |
| GroupedDBID | - 23M 53G 55A 5GY 7~N AABXI ABMVS ABUCX ACGFS ACS AEESW AENEX AFEFF ALMA_UNASSIGNED_HOLDINGS AQSVZ EBS ED ED~ F5P GNL IH9 JG JG~ P2P RNS ROL UI2 VF5 VG9 W1F XKZ --- .K2 4.4 5VS 5ZA 6J9 AAHBH ABJNI ABQRX ADHLV AHGAQ BAANH CUPRZ GGK NPM AAYXX CITATION 7X8 5PM |
| ID | FETCH-LOGICAL-a425t-1e66ac84952897922ca13048de41f8cc8b1983c656ab9b99270574225a8599e83 |
| IEDL.DBID | ACS |
| ISSN | 1944-8244 |
| IngestDate | Tue Sep 17 21:24:49 EDT 2024 Sat Aug 17 00:13:16 EDT 2024 Fri Aug 23 02:36:54 EDT 2024 Sat Sep 28 08:25:27 EDT 2024 Thu Aug 27 13:43:41 EDT 2020 |
| IsDoiOpenAccess | false |
| IsOpenAccess | true |
| IsPeerReviewed | true |
| IsScholarly | true |
| Issue | 50 |
| Keywords | electrochemical neutron reflectometry scattering length density solid electrolyte interphase diethyl carbonate differential evolution adaptive metropolis lithium-ion battery ethylene carbonate X-ray reflectometry |
| Language | English |
| LinkModel | DirectLink |
| MergedId | FETCHMERGED-LOGICAL-a425t-1e66ac84952897922ca13048de41f8cc8b1983c656ab9b99270574225a8599e83 |
| Notes | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
| ORCID | 0000-0001-5031-6888 0000-0001-6877-959X |
| OpenAccessLink | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7470620 |
| PMID | 31815415 |
| PQID | 2323471636 |
| PQPubID | 23479 |
| PageCount | 11 |
| ParticipantIDs | pubmedcentral_primary_oai_pubmedcentral_nih_gov_7470620 proquest_miscellaneous_2323471636 crossref_primary_10_1021_acsami_9b16592 pubmed_primary_31815415 acs_journals_10_1021_acsami_9b16592 |
| ProviderPackageCode | JG~ 55A AABXI GNL VF5 XKZ 7~N VG9 W1F ACS AEESW AFEFF ABMVS ABUCX IH9 AQSVZ ED~ UI2 |
| PublicationCentury | 2000 |
| PublicationDate | 2019-12-18 |
| PublicationDateYYYYMMDD | 2019-12-18 |
| PublicationDate_xml | – month: 12 year: 2019 text: 2019-12-18 day: 18 |
| PublicationDecade | 2010 |
| PublicationPlace | United States |
| PublicationPlace_xml | – name: United States |
| PublicationTitle | ACS applied materials & interfaces |
| PublicationTitleAlternate | ACS Appl. Mater. Interfaces |
| PublicationYear | 2019 |
| Publisher | American Chemical Society |
| Publisher_xml | – name: American Chemical Society |
| References | ref9/cit9 ref3/cit3 ref27/cit27 ref63/cit63 ref56/cit56 Irene E. A. (ref57/cit57) 2005 ref16/cit16 ref52/cit52 ref23/cit23 ref8/cit8 ref31/cit31 ref59/cit59 ref2/cit2 ref34/cit34 ref71/cit71 ref37/cit37 ref20/cit20 ref48/cit48 ref60/cit60 ref74/cit74 ref17/cit17 ref35/cit35 ref53/cit53 ref19/cit19 ref21/cit21 ref42/cit42 ref46/cit46 ref49/cit49 ref13/cit13 Naidu S. V. N. (ref45/cit45) 1990 ref61/cit61 ref75/cit75 ref67/cit67 ref24/cit24 ref38/cit38 ref50/cit50 ref54/cit54 ref6/cit6 ref36/cit36 ref18/cit18 ref65/cit65 ref11/cit11 ref25/cit25 ref72/cit72 ref76/cit76 ref32/cit32 ref39/cit39 ref14/cit14 ref5/cit5 ref51/cit51 ref43/cit43 ref28/cit28 ref40/cit40 ref68/cit68 Dura J. A. (ref10/cit10) 2017 ref26/cit26 ref55/cit55 ref73/cit73 ref69/cit69 ref12/cit12 ref15/cit15 ref62/cit62 ref66/cit66 ref41/cit41 ref58/cit58 ref22/cit22 ref33/cit33 ref4/cit4 ref30/cit30 ref47/cit47 ref1/cit1 ref44/cit44 Rumble J. R. (ref64/cit64) 2018 ref70/cit70 ref7/cit7 |
| References_xml | – ident: ref8/cit8 doi: 10.1039/C7EE02555F – ident: ref41/cit41 doi: 10.1016/S0921-5093(00)00745-0 – ident: ref48/cit48 doi: 10.1107/S0365110X59000767 – volume-title: Binary Alloy Phase Diagrams year: 1990 ident: ref45/cit45 contributor: fullname: Naidu S. V. N. – ident: ref28/cit28 doi: 10.1016/j.jpowsour.2018.11.093 – ident: ref36/cit36 – ident: ref76/cit76 doi: 10.1016/0921-4526(94)90156-2 – ident: ref18/cit18 doi: 10.1016/j.apsusc.2017.01.290 – ident: ref22/cit22 doi: 10.5796/electrochemistry.78.413 – ident: ref67/cit67 doi: 10.1107/S0108768186098476 – ident: ref6/cit6 doi: 10.1039/C7CS00180K – ident: ref68/cit68 doi: 10.1107/S0108768105003629 – ident: ref33/cit33 – ident: ref60/cit60 doi: 10.1016/S0022-0728(74)80377-3 – ident: ref38/cit38 doi: 10.1515/IJNSNS.2009.10.3.273 – ident: ref71/cit71 doi: 10.1149/1.1838420 – ident: ref46/cit46 doi: 10.1063/1.333738 – ident: ref73/cit73 doi: 10.1039/C0SM00558D – ident: ref26/cit26 doi: 10.1080/10448639208218770 – ident: ref42/cit42 doi: 10.1063/1.4803699 – ident: ref53/cit53 doi: 10.1021/ic50035a033 – ident: ref62/cit62 – ident: ref32/cit32 doi: 10.1063/1.2219744 – ident: ref4/cit4 doi: 10.1021/cm3006887 – ident: ref12/cit12 doi: 10.1039/c3cp44438d – ident: ref27/cit27 doi: 10.1021/cr500207g – ident: ref47/cit47 doi: 10.1107/S0021889890003636 – ident: ref15/cit15 doi: 10.1039/C6CP00978F – ident: ref16/cit16 doi: 10.1021/acsnano.6b02032 – ident: ref51/cit51 doi: 10.1006/jssc.1999.8173 – ident: ref31/cit31 doi: 10.1016/0040-6090(82)90147-X – ident: ref5/cit5 doi: 10.1021/acs.jpclett.5b01727 – ident: ref35/cit35 doi: 10.1016/j.cocis.2011.11.001 – ident: ref7/cit7 doi: 10.1016/j.electacta.2010.05.072 – ident: ref70/cit70 doi: 10.1021/ac60156a007 – volume-title: CRC Handbook of Chemistry and Physics year: 2018 ident: ref64/cit64 contributor: fullname: Rumble J. R. – ident: ref50/cit50 doi: 10.1016/0022-4596(79)90199-3 – ident: ref9/cit9 doi: 10.1016/S0378-7753(01)00826-6 – ident: ref63/cit63 doi: 10.1021/jp047240b – ident: ref40/cit40 doi: 10.1023/A:1010143904328 – ident: ref37/cit37 – ident: ref13/cit13 doi: 10.1039/c3cc49269a – ident: ref58/cit58 doi: 10.1063/1.122442 – ident: ref61/cit61 doi: 10.1016/S0022-0728(72)80485-6 – ident: ref19/cit19 doi: 10.1016/j.joule.2018.12.013 – ident: ref75/cit75 doi: 10.1021/la402496z – start-page: 155 volume-title: Nanolayer Research year: 2017 ident: ref10/cit10 doi: 10.1016/B978-0-444-63739-0.00005-0 contributor: fullname: Dura J. A. – ident: ref21/cit21 doi: 10.1016/j.apsusc.2019.04.241 – ident: ref43/cit43 doi: 10.1016/j.actamat.2015.11.049 – ident: ref74/cit74 doi: 10.1021/la303837c – ident: ref17/cit17 doi: 10.1021/acsami.7b09181 – ident: ref24/cit24 doi: 10.1088/1742-6596/502/1/012054 – ident: ref69/cit69 doi: 10.1088/0953-8984/3/26/001 – ident: ref66/cit66 doi: 10.1524/zkri.1979.150.1-4.133 – ident: ref11/cit11 doi: 10.1021/acsami.6b01170 – ident: ref14/cit14 doi: 10.1021/acs.jpcc.5b06817 – ident: ref25/cit25 doi: 10.1021/acs.jpcc.6b02523 – ident: ref34/cit34 doi: 10.1107/S1600576718011974 – ident: ref39/cit39 doi: 10.1039/C4SM00850B – ident: ref52/cit52 doi: 10.1107/S0567739475000745 – ident: ref54/cit54 doi: 10.1107/S0567740869004146 – ident: ref65/cit65 doi: 10.1107/S0567739478001151 – ident: ref23/cit23 doi: 10.1021/am5032055 – ident: ref2/cit2 doi: 10.1149/2.1441707jes – ident: ref44/cit44 doi: 10.1116/1.4936261 – ident: ref55/cit55 doi: 10.1088/0953-8984/10/33/002 – ident: ref72/cit72 doi: 10.1038/s41565-018-0284-y – ident: ref59/cit59 doi: 10.1149/1.2123617 – ident: ref3/cit3 doi: 10.1021/cr030203g – ident: ref49/cit49 doi: 10.1016/0025-5408(74)90120-2 – start-page: 569 volume-title: Handbook of Ellipsometry year: 2005 ident: ref57/cit57 contributor: fullname: Irene E. A. – ident: ref1/cit1 doi: 10.1149/1.2128859 – ident: ref20/cit20 doi: 10.1021/acs.nanolett.6b02926 – ident: ref30/cit30 doi: 10.1149/1.1353568 – ident: ref56/cit56 doi: 10.1143/JJAP.35.L67 |
| SSID | ssj0063205 |
| Score | 2.461031 |
| Snippet | Tungsten, a non-Li-intercalating material, was used as a platform to study solid–electrolyte interface/interphase (SEI) formation in lithium hexafluorphosphate... Tungsten, a non-Li-intercalating material, was used as a platform to study solid-electrolyte interface/interphase (SEI) formation in lithium hexafluorphosphate... |
| SourceID | pubmedcentral proquest crossref pubmed acs |
| SourceType | Open Access Repository Aggregation Database Index Database Publisher |
| StartPage | 47553 |
| Title | In Situ Neutron Reflectometry Study of Solid Electrolyte Interface (SEI) Formation on Tungsten Thin-Film Electrodes |
| URI | http://dx.doi.org/10.1021/acsami.9b16592 https://www.ncbi.nlm.nih.gov/pubmed/31815415 https://search.proquest.com/docview/2323471636 https://pubmed.ncbi.nlm.nih.gov/PMC7470620 |
| Volume | 11 |
| hasFullText | 1 |
| inHoldings | 1 |
| isFullTextHit | |
| isPrint | |
| link | http://sdu.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwjV1LT4QwEJ74uOjB92N9pUYT9UBcWijt0ehu9OJBNPFG2lIiyS5rBA77753CYlyNiQkHEgqBfu3M93XKDMA51drQVKLI0Tz1Amb6njQaAVFoMFPFDLUuonsfR4-v4m7g0uRc_hHBp_61MqUrhSO17yKAi7BMI6QJjgTdxp3N5Yw2mxVRkQeeQI_VpWf8db9zQqacd0K_mOXPDZLfPM5w_f_vugFrM1ZJbtphsAkLttiC1W-5BrehfChInFc1ebS1W_4mTzZrluzHtvqYErefcEomGYknozwlg7Y6zmhaWdIsGmbKWHIZDx6uyLD735Hg8YzGAgcKnrzlhTfMR-Pu3tSWO_AyHDzf3nuziguewrlbeb7lXBmBogl1WCQpNQ6yQKQ28DNhjNC-FMwgB1RaaikRihC1NQ2VCKW0gu3CUjEp7D4QnmkZSmtYFkRBppnsI_PkMhDKyTyuenCGvZXMZkyZNMFw6idtFyazLuzBRQdU8t6m3_iz5WmHY4IzxIU9VGEndZkgZ2TogjnjPdhrcf16Flo05JB-2INoDvGvBi779vyVIn9rsnCjDutz2j_413ccwgoyrabwhC-OYKn6qO0xLJZpfdIM5E_taO5z |
| link.rule.ids | 230,315,782,786,887,2769,27085,27933,27934,56747,56797 |
| linkProvider | American Chemical Society |
| linkToHtml | http://sdu.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwlV3dT9swED_x8bDxwPgY0G2A0ZCAh4jGTh37cYJWrYA-LJ3EW2Q7johUUkSSh_73OycNo6BJm5SHKLEt23e--53PvgM4pVobmkg0cjRPvICZrieNRoIoFJiJYoZa59EdRuH4Xlz3XZicy_YuDHaiwJaK2on_J7qAf4nfXEYcqX3nCFyF9R5HJOyw0FXUil7OaH1mEQ3zwBOouNooje_qO11kimVd9A5gvj0n-UrxDD79d5e3YHOBMcmPhim2YcXmO7DxKvLgLhSjnERZWZGxrdxmOPlp03oD_9GWz3PiThfOySwl0WyaJaTf5MqZzktL6i3EVBlLzqP-6IIM2tuPBJ8Jig5kG3x5yHJvkE0f27qJLT7Dr0F_cjX0FvkXPIUrufR8y7kyAk0otMpCSalxBAxEYgM_FcYI7UvBDCJCpaWWkoYI_gIUEEr0pLSC7cFaPsvtARCeatmT1rA0CINUM9lFHMplIJQz-rjqwHecrXixfoq4do1TP26mMF5MYQfOWnrFT00wjr-WPGnJGeN6cU4QldtZVcSIIBkqZM54B_Yb8r60hfINEaXf60C4RPiXAi4W9_KfPHuoY3IjL3Y57X75p3Ecw4fh5O42vh2Nb77CR8RgdUoKX3yDtfK5soewWiTVUc3bvwEpzfbg |
| linkToPdf | http://sdu.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV3da9swED_WDEr3sK-2W_ap0ULbB9NYcmTpsbQxDRth1C3szUiyTAypU2L7If_9Tv4ozcqgFPxgbElIOt3d73TSHcAh1drQVKKRo3nqBcyMPGk0EkShwEwVM9Q6j-5lHM7-iIuJC5PD-rsw2IkSWyobJ77j6rs06yIM-Kf43WXFkdp3zsAteDnmoXQW19l53ItfzmhzbhGN88ATqLz6SI2P6jt9ZMpNffQIZP57VvKB8onePKvbb-F1hzXJWbs43sELW7yHVw8iEO5COS1InFc1mdnabYqTK5s1G_m3tlqtiTtluCbLjMTLRZ6SSZszZ7GuLGm2EjNlLDmOJ9MTEvW3IAk-1yhCcPngyzwvvChf3PZ1U1vuwU00uT6_9Lo8DJ5Cjq4833KujEBTCq2zUFJqHCEDkdrAz4QxQvtSMIPIUGmppaQhgsAABYUSYymtYPswKJaF_QiEZ1qOpTUsC8Ig00yOEI9yGQjljD-uhnCAs5V0fFQmjYuc-kk7hUk3hUM46mmW3LVBOf5b8kdP0gT5xjlDVGGXdZkgkmSomDnjQ_jQkvi-LZRziCz98RDCDeLfF3AxuTf_FPm8ic2N1tmI09GnJ43jO2z_voiSX9PZz8-wg1CsyUzhiy8wqFa1_QpbZVp_a5b3Xzeu-WM |
| openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=In+Situ+Neutron+Reflectometry+Study+of+Solid+Electrolyte+Interface+%28SEI%29+Formation+on+Tungsten+Thin-Film+Electrodes&rft.jtitle=ACS+applied+materials+%26+interfaces&rft.au=Rus%2C+Eric+D&rft.au=Dura%2C+Joseph+A&rft.date=2019-12-18&rft.eissn=1944-8252&rft.volume=11&rft.issue=50&rft.spage=47553&rft.epage=47563&rft_id=info:doi/10.1021%2Facsami.9b16592&rft.externalDBID=NO_FULL_TEXT |
| thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=1944-8244&client=summon |
| thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=1944-8244&client=summon |
| thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=1944-8244&client=summon |