EXAFS Investigation of U(VI), U(IV), and Th(IV) Sulfato Complexes in Aqueous Solution

The local structure of U(VI), U(IV), and Th(IV) sulfato complexes in aqueous solution was investigated by U-L3 and Th-L3 EXAFS spectroscopy for total sulfate concentrations 0.05 ≤ [SO4 2-] ≤ 3 M and 1.0 ≤ pH ≤ 2.6. The sulfate coordination was derived from U−S and Th−S distances and coordination num...

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Bibliographic Details
Published in:Inorganic chemistry Vol. 46; no. 15; pp. 5882 - 5892
Main Authors: Hennig, Christoph, Schmeide, Katja, Brendler, Vinzenz, Moll, Henry, Tsushima, Satoru, Scheinost, Andreas C
Format: Journal Article
Language:English
Published: United States American Chemical Society 23-07-2007
Online Access:Get full text
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