Electrostatic Heteroaggregation: Fundamentals and Applications in Interfacial Engineering

• Published in: Langmuir Vol. 39; no. 6; pp. 2112 - 2134
• Main Authors: Madhavan, Nithin, Deshpande, Abhijit P., Mani, Ethayaraja, Basavaraj, Madivala G.
• Format: Journal Article
• Language: English
• Published: United States American Chemical Society 14-02-2023
• ISSN: 0743-7463; 1520-5827
• DOI: 10.1021/acs.langmuir.2c02681

The aggregation of oppositely charged soft materials (particles, surfactants, polyelectrolytes, etc.) that differ in one or more physical or chemical attributes, broadly referred to as electrostatic heteroaggregation, has been an active area of research for several decades now. While electrostatic heteroaggregation (EHA) is relevant to diverse fields such as environmental engineering, food technology, and pharmaceutical formulations, more recently there has been a resurgence to explore various aspects of this phenomenon in the context of interface stabilization and the development of functional materials. In this Feature Article, we provide an overview of the recent contributions of our group to this exciting field with particular emphasis on fundamental studies of electrostatic heteroaggregation between oppositely charged systems in the bulk, at interfaces, and across the bulk/interface. The influence of the size and shape of particles and the surface charge of heteroaggregates on the formation of Pickering emulsions and their utilization in the development of porous ceramics is discussed.