Coexistence of Spin Canting and Metamagnetism in a One-Dimensional Mn(III) Complex Bridged by a Single End-to-End Azide

Coexistence of Spin Canting and Metamagnetism in a One-Dimensional Mn(III) Complex Bridged by a Single End-to-End Azide

Two manganese(III) azide complexes capped with tetradentate Schiff bases were characterized structurally and magnetically. The replacement of halogens on the Schiff bases leads to a drastic structural alteration from a dimer (1) bridged by phenoxide to a one-dimensional chain (2) linked by azide in...

Full description

Saved in:
Bibliographic Details
Published in:Inorganic chemistry Vol. 45; no. 22; pp. 8847 - 8849
Main Authors: Ko, Hyun Hee, Lim, Jeong Hak, Kim, Hyoung Chan, Hong, Chang Seop
Format: Journal Article
Language:English
Published: United States American Chemical Society 30-10-2006
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Two manganese(III) azide complexes capped with tetradentate Schiff bases were characterized structurally and magnetically. The replacement of halogens on the Schiff bases leads to a drastic structural alteration from a dimer (1) bridged by phenoxide to a one-dimensional chain (2) linked by azide in a single end-to-end mode. Notably, magnetic studies of 2 show the concomitant existence of spin canting and metamagnetism.
Bibliography:ark:/67375/TPS-20W5H6DK-W
istex:7BFC507A75DFC16500C604E6833DDFC2E1CE1FE7
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:0020-1669
1520-510X
DOI:10.1021/ic061415+