Synthesis of B/Si Bidentate Lewis Acids, o‑(Fluorosilyl)borylbenzenes and o‑(Difluorosilyl)borylbenzenes, and Their Fluoride Ion Affinities

Herein, we report detailed studies on a series of o-(silyl)­(boryl)­benzenes (1–4), in which the two Lewis acid centers consisting of silicon and boron atoms are linked via an o-phenylene skeleton. o-(Fluorosilyl)­(dimesitylboryl)­benzenes 1 and 2 were prepared by the reaction of fluorodimesitylbora...

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Bibliographic Details

Published in:	ACS omega Vol. 7; no. 35; pp. 30939 - 30953
Main Authors:	Shimada, Junpei, Tani, Atsushi, Hanazato, Chihiro, Masuyama, Takashi, Yamamoto, Yohsuke, Kawachi, Atsushi
Format:	Journal Article
Language:	English
Published:	American Chemical Society 06-09-2022
Online Access:	Get full text
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