4-D ground penetrating radar monitoring of a hydrocarbon leakage site in Fortaleza (Brazil) during its remediation process: a case history
A 4-D monitoring GPR survey was carried out in order to outline the light non-aqueous phase liquid (LNAPL) plume underground during a remediation process in the area of an impacted gas station in Fortaleza, NE Brazil. The complex GPR signature of the plume was well characterized. Low reflectivity zo...
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Published in: | Journal of applied geophysics Vol. 54; no. 1; pp. 127 - 144 |
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Abstract | A 4-D monitoring GPR survey was carried out in order to outline the light non-aqueous phase liquid (LNAPL) plume underground during a remediation process in the area of an impacted gas station in Fortaleza, NE Brazil. The complex GPR signature of the plume was well characterized. Low reflectivity zone corresponds to hydrocarbon vapor phase in the vadose zone. Enhanced reflections are associated with free and residual products directly above the water table. A theoretical model based on geochemical zonation of the LNAPL was calculated using a finite difference time domain (FDTD) forward modeling code, whose synthetic radargrams provide useful insight into the nature of the reflection events related to LNAPL contamination. Hydrogeologic and hydrochemical data from installed monitoring wells provided additional support for interpreting of the GPR response. Moreover, a network of radar sections collected during fifteen months at the polluted site show clearly temporal changes in the plume dimensions, induced by regular pumping of groundwater. This corrective action caused an important drop of the water table that was followed by a rapid shrinking of the impacted area in the vadose zone, generating pooling of vapor products. A steady restore of the reflectivity in the shadow zone suggests a decrease of LNAPL saturation along the GPR survey. |
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AbstractList | A 4-D monitoring GPR survey was carried out in order to outline the light non-aqueous phase liquid (LNAPL) plume underground during a remediation process in the area of an impacted gas station in Fortaleza, NE Brazil. The complex GPR signature of the plume was well characterized. Low reflectivity zone corresponds to hydrocarbon vapor phase in the vadose zone. Enhanced reflections are associated with free and residual products directly above the water table. A theoretical model based on geochemical zonation of the LNAPL was calculated using a finite difference time domain (FDTD) forward modeling code, whose synthetic radargrams provide useful insight into the nature of the reflection events related to LNAPL contamination. Hydrogeologic and hydrochemical data from installed monitoring wells provided additional support for interpreting of the GPR response. Moreover, a network of radar sections collected during fifteen months at the polluted site show clearly temporal changes in the plume dimensions, induced by regular pumping of groundwater. This corrective action caused an important drop of the water table that was followed by a rapid shrinking of the impacted area in the vadose zone, generating pooling of vapor products. A steady restore of the reflectivity in the shadow zone suggests a decrease of LNAPL saturation along the GPR survey. |
Author | Lopes de Castro, David Branco, Raimundo Mariano Gomes Castelo |
Author_xml | – sequence: 1 givenname: David surname: Lopes de Castro fullname: Lopes de Castro, David email: david@ufc.br – sequence: 2 givenname: Raimundo Mariano Gomes Castelo surname: Branco fullname: Branco, Raimundo Mariano Gomes Castelo email: mariano@ufc.br |
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Cites_doi | 10.1063/1.335804 10.1111/j.1365-2478.1989.tb02221.x 10.1016/S0926-9851(99)00021-X 10.1190/1.1444148 10.1190/1.1444746 10.1109/36.729364 10.1046/j.1365-2478.2000.00187.x 10.1016/0926-9851(95)90041-1 |
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Keywords | Ground penetrating radar 4-D survey Hydrocarbon leakage Forward modeling South America models hydrocarbons plumes liquid phase water table pollution vapor phase ground-penetrating radar contamination pumping saturation remediation zoning leakage |
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References_xml | – volume: 36 start-page: 1928 year: 1998 end-page: 1937 ident: BIB19 article-title: Finite-difference time-domain simulation of ground penetrating radar on dispersive, inhomogeneous, and conductive soils publication-title: IEEE Transactions on Geoscience and Remote Sensing contributor: fullname: Wang – year: 1982 ident: BIB1 article-title: Basic well log analysis for geologists publication-title: AAPG contributor: fullname: Gibson – year: 1990 ident: BIB11 article-title: Physical and Chemical Hydrogeology contributor: fullname: Schwartz – volume: 64 start-page: 80 year: 1997 end-page: 86 ident: BIB2 article-title: Mapping groundwater contamination using dc resistivity and VLF geophysical methods—a case study publication-title: Geophysics contributor: fullname: Stubben – volume: 58 start-page: 3236 year: 1985 end-page: 3242 ident: BIB12 article-title: Geometrical model of conductive and dielectric properties of partially saturated rocks publication-title: Journal of Applied Physics contributor: fullname: Sem – start-page: 1283 year: 1994 end-page: 1294 ident: BIB15 article-title: Detection of LNAPL pools with GPR: theoretical modeling and surveys of a controlled spill publication-title: Proceedings of the Fifth International Conference on Ground Penetrating Radar (GPR'94), Kitchener, Ontario, Canada, Expanded Abstract contributor: fullname: Annan – start-page: 284 year: 1986 end-page: 305 ident: BIB14 article-title: Direct detection of hydrocarbon and organic chemicals with ground penetrating radar and complex resistivity publication-title: Proc. 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causada por vazamentos em postos de abastecimento contributor: fullname: Guiger – volume: 65 start-page: 521 year: 2000 end-page: 525 ident: BIB6 article-title: GPR modeling study in a contaminated area of Krzywa air base (Poland) publication-title: Geophysics contributor: fullname: Padoan – volume: 44 start-page: 151 year: 2000 end-page: 165 ident: BIB16 article-title: A model for the resistivity structure of LNAPL plumes and their environs in sandy sediments publication-title: Journal of Applied Geophysics contributor: fullname: Sauck – volume: 48 start-page: 231 year: 2000 end-page: 256 ident: BIB5 article-title: An electromagnetic modelling tool for the detection of hydrocarbons in the subsoil publication-title: Geophysical Prospecting contributor: fullname: Seriani – start-page: 24 year: 2000 end-page: 31 ident: BIB7 article-title: Results of a natural attenuation field experiment for an ethanol-blended gasoline spill publication-title: Proceedings of the 2000 petroleum hydrocarbon and organic chemicals in ground water contributor: fullname: Seabra – volume: vol. 2 start-page: 597 year: 1992 end-page: 609 ident: BIB8 article-title: Site studies of ground penetrating radar for monitoring petroleum product contaminants publication-title: Proceedings of the symposium application of geophysics to engineering and environmental problems (SAGEEP'92) contributor: fullname: Vendl – year: 1988 ident: BIB17 article-title: Dense Chlorinated Solvents in Porous and Fractured Media contributor: fullname: Schwille – volume: 58 start-page: 3236 year: 1985 ident: 10.1016/j.jappgeo.2003.08.021_BIB12 article-title: Geometrical model of conductive and dielectric properties of partially saturated rocks publication-title: Journal of Applied Physics doi: 10.1063/1.335804 contributor: fullname: Feng – volume: vol. 2 start-page: 597 year: 1992 ident: 10.1016/j.jappgeo.2003.08.021_BIB8 article-title: Site studies of ground penetrating radar for monitoring petroleum product contaminants contributor: fullname: Daniels – ident: 10.1016/j.jappgeo.2003.08.021_BIB3 – volume: 37 start-page: 531 year: 1989 ident: 10.1016/j.jappgeo.2003.08.021_BIB10 article-title: Ground-penetrating radar for high-resolution mapping of soil and rock stratigraphy publication-title: Geophysical Prospecting doi: 10.1111/j.1365-2478.1989.tb02221.x contributor: fullname: Davis – year: 1988 ident: 10.1016/j.jappgeo.2003.08.021_BIB17 contributor: fullname: Schwille – volume: 44 start-page: 151 year: 2000 ident: 10.1016/j.jappgeo.2003.08.021_BIB16 article-title: A model for the resistivity structure of LNAPL plumes and their environs in sandy sediments publication-title: Journal of Applied Geophysics doi: 10.1016/S0926-9851(99)00021-X contributor: fullname: Sauck – volume: 64 start-page: 80 issue: 1 year: 1997 ident: 10.1016/j.jappgeo.2003.08.021_BIB2 article-title: Mapping groundwater contamination using dc resistivity and VLF geophysical methods—a case study publication-title: Geophysics doi: 10.1190/1.1444148 contributor: fullname: Benson – volume: 65 start-page: 521 issue: 2 year: 2000 ident: 10.1016/j.jappgeo.2003.08.021_BIB6 article-title: GPR modeling study in a contaminated area of Krzywa air base (Poland) publication-title: Geophysics doi: 10.1190/1.1444746 contributor: fullname: Carcione – volume: 36 start-page: 1928 issue: 6 year: 1998 ident: 10.1016/j.jappgeo.2003.08.021_BIB19 article-title: Finite-difference time-domain simulation of ground penetrating radar on dispersive, inhomogeneous, and conductive soils publication-title: IEEE Transactions on Geoscience and Remote Sensing doi: 10.1109/36.729364 contributor: fullname: Teixeira – year: 1990 ident: 10.1016/j.jappgeo.2003.08.021_BIB11 contributor: fullname: Domenico – year: 2000 ident: 10.1016/j.jappgeo.2003.08.021_BIB13 contributor: fullname: Guiger – start-page: 511 year: 1996 ident: 10.1016/j.jappgeo.2003.08.021_BIB4 article-title: Monitoring of a controlled LNAPL spill using ground penetrating radar contributor: fullname: Campbell – start-page: 284 year: 1986 ident: 10.1016/j.jappgeo.2003.08.021_BIB14 article-title: Direct detection of hydrocarbon and organic chemicals with ground penetrating radar and complex resistivity contributor: fullname: Olhoeft – start-page: 1283 year: 1994 ident: 10.1016/j.jappgeo.2003.08.021_BIB15 article-title: Detection of LNAPL pools with GPR: theoretical modeling and surveys of a controlled spill contributor: fullname: Redman – volume: 48 start-page: 231 issue: 2 year: 2000 ident: 10.1016/j.jappgeo.2003.08.021_BIB5 article-title: An electromagnetic modelling tool for the detection of hydrocarbons in the subsoil publication-title: Geophysical Prospecting doi: 10.1046/j.1365-2478.2000.00187.x contributor: fullname: Carcione – ident: 10.1016/j.jappgeo.2003.08.021_BIB18 – start-page: 24 year: 2000 ident: 10.1016/j.jappgeo.2003.08.021_BIB7 article-title: Results of a natural attenuation field experiment for an ethanol-blended gasoline spill contributor: fullname: Corseuil – volume: 33 start-page: 195 year: 1995 ident: 10.1016/j.jappgeo.2003.08.021_BIB9 article-title: Ground penetrating radar for the detection of liquid contaminants publication-title: Journal of Applied Geophysics doi: 10.1016/0926-9851(95)90041-1 contributor: fullname: Daniels – year: 1982 ident: 10.1016/j.jappgeo.2003.08.021_BIB1 article-title: Basic well log analysis for geologists publication-title: AAPG contributor: fullname: Asquith |
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SubjectTerms | 4-D survey Applied geophysics Earth sciences Earth, ocean, space Engineering and environment geology. Geothermics Exact sciences and technology Forward modeling Ground penetrating radar Hydrocarbon leakage Internal geophysics Pollution, environment geology |
Title | 4-D ground penetrating radar monitoring of a hydrocarbon leakage site in Fortaleza (Brazil) during its remediation process: a case history |
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