Introducing Environmental and Sustainable Chemistry Topics Using a Nanotechnology Approach: Removing Hazardous Metal Ions by Means of Humic-Acid-Modified Superparamagnetic Nanoparticles
A laboratory experiment has been developed to illustrate environmental and sustainability aspects, focusing on the wastewater treatment by means of superparamagnetic nanoparticles functionalized with humic acid. The experiment, conducted by a group of high school students, involves nanoparticle synt...
Saved in:
| Published in: | Journal of chemical education Vol. 93; no. 11; pp. 1929 - 1934 |
|---|---|
| Main Authors: | , , , , , , , |
| Format: | Journal Article |
| Language: | English |
| Published: |
Easton
American Chemical Society and Division of Chemical Education, Inc
08-11-2016
Division of Chemical Education, Inc and ACS Publications Division of the American Chemical Society American Chemical Society |
| Subjects: | |
| Online Access: | Get full text |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| Abstract | A laboratory experiment has been developed to illustrate environmental and sustainability aspects, focusing on the wastewater treatment by means of superparamagnetic nanoparticles functionalized with humic acid. The experiment, conducted by a group of high school students, involves nanoparticle synthesis and minor characterization, followed by their interaction with typical metal ion contaminants in water. Coordination chemistry concepts were explored to help students understand the experiment, using competitive agents, such as ammonia, for recovering and recycling the nanoparticles, highlighting the great affinity of humic acid for the metal ions. |
|---|---|
| AbstractList | A laboratory experiment has been developed to illustrate environmental and sustainability aspects, focusing on the wastewater treatment by means of superparamagnetic nanoparticles functionalized with humic acid. The experiment, conducted by a group of high school students, involves nanoparticle synthesis and minor characterization, followed by their interaction with typical metal ion contaminants in water. Coordination chemistry concepts were explored to help students understand the experiment, using competitive agents, such as ammonia, for recovering and recycling the nanoparticles, highlighting the great affinity of humic acid for the metal ions. |
| Audience | High Schools Secondary Education |
| Author | Prado, Caio Cesar Pestana Silveira, Alceu Totti da Silva, Delmárcio Gomes de Melo, Fernando Menegatti Toma, Henrique Eisi da Cruz, Bruno Constancio de Vasconcelos, Luana Cristina Pereira Amaral Sanches Lucas, Vitor |
| AuthorAffiliation | Departamento Química Fundamental, Instituto de Química Etec Osasco II Universidade de São Paulo |
| AuthorAffiliation_xml | – name: Etec Osasco II – name: Universidade de São Paulo – name: Departamento Química Fundamental, Instituto de Química |
| Author_xml | – sequence: 1 givenname: Delmárcio Gomes surname: da Silva fullname: da Silva, Delmárcio Gomes – sequence: 2 givenname: Fernando Menegatti surname: de Melo fullname: de Melo, Fernando Menegatti – sequence: 3 givenname: Alceu Totti surname: Silveira fullname: Silveira, Alceu Totti – sequence: 4 givenname: Bruno Constancio surname: da Cruz fullname: da Cruz, Bruno Constancio – sequence: 5 givenname: Caio Cesar Pestana surname: Prado fullname: Prado, Caio Cesar Pestana – sequence: 6 givenname: Luana Cristina Pereira surname: de Vasconcelos fullname: de Vasconcelos, Luana Cristina Pereira – sequence: 7 givenname: Vitor surname: Amaral Sanches Lucas fullname: Amaral Sanches Lucas, Vitor – sequence: 8 givenname: Henrique Eisi surname: Toma fullname: Toma, Henrique Eisi email: henetoma@iq.usp.br |
| BackLink | http://eric.ed.gov/ERICWebPortal/detail?accno=EJ1119661$$DView record in ERIC |
| BookMark | eNp9kV9r2zAUxcXoYGm3TzAGgj07lfxX2lsI6ZLRbrC1z-ZavkoUbMmT7EL2zfbtJjehj3vSle75nYM41-TKOouEfORsyVnKb0GF5VEdsMd2WTaM8Sp9QxZcZiLhWSquyIJFWSILkb8j1yEcoyQtpFiQvzs7etdOytg93dhn453t0Y7QUbAt_TWFEYyFpkO6jv4mjP5EH91gVKBPYYaAfgfrRlQH6zq3P9HVMHgH6vCF_sTePc-aLfwB37op0AecrXfOBtqc4g3i4DTdTr1RyUqZNnlwrdEG5-wB_QAeethbHI16CYoPcewwvCdvNXQBP1zOG_J0t3lcb5P7H19369V9AjkrxqRsNMpc5WWpFRdphkUrcikaUTWZLCpdNZJXjQYmVc5kKgqlldaYZ5K1OkWd3ZDPZ9_4q98ThrE-usnbGFlzUVUV50xUUZWdVcq7EDzqevCmB3-qOavnjurYUX3pqL50FKlPZwq9Ua_E5hvnXJYlj_vb8_4Ffo39j-M_DUen6w |
| CODEN | JCEDA8 |
| CitedBy_id | crossref_primary_10_1021_acs_jchemed_7b00345 crossref_primary_10_1021_acs_jchemed_9b00384 crossref_primary_10_1007_s11356_019_04691_4 crossref_primary_10_1021_acs_jchemed_0c01418 crossref_primary_10_1039_D1NA00149C crossref_primary_10_1021_acs_jchemed_3c00685 crossref_primary_10_29333_ejmste_13834 crossref_primary_10_1021_acsanm_8b00502 crossref_primary_10_1021_acs_analchem_2c00457 |
| Cites_doi | 10.1021/ed073p1183 10.1021/ed200150f 10.1016/j.envpol.2010.03.024 10.1006/eesa.2000.1947 10.1021/ed079p715 10.1021/ed100010c 10.1016/B978-012656446-4/50001-3 10.1016/j.envpol.2007.11.015 10.1021/ed500246s 10.1351/PAC-CON-12-12-02 10.1016/j.scitotenv.2013.09.044 10.1016/j.seppur.2005.12.022 10.1038/nature06599 10.1016/j.jclepro.2007.04.018 10.1016/0016-7037(80)90221-5 10.1016/j.jenvman.2010.11.011 10.1039/C5GC00066A 10.1016/j.jmmm.2015.08.092 10.1016/j.jmmm.2006.05.001 |
| ContentType | Journal Article |
| Copyright | Copyright © 2016 American
Chemical Society and Division of Chemical Education, Inc. Copyright American Chemical Society Nov 8, 2016 |
| Copyright_xml | – notice: Copyright © 2016 American Chemical Society and Division of Chemical Education, Inc. – notice: Copyright American Chemical Society Nov 8, 2016 |
| DBID | 7SW BJH BNH BNI BNJ BNO ERI PET REK WWN AAYXX CITATION K9. |
| DOI | 10.1021/acs.jchemed.6b00172 |
| DatabaseName | ERIC ERIC (Ovid) ERIC ERIC ERIC (Legacy Platform) ERIC( SilverPlatter ) ERIC ERIC PlusText (Legacy Platform) Education Resources Information Center (ERIC) ERIC CrossRef ProQuest Health & Medical Complete (Alumni) |
| DatabaseTitle | ERIC CrossRef ProQuest Health & Medical Complete (Alumni) |
| DatabaseTitleList | ProQuest Health & Medical Complete (Alumni) ERIC |
| Database_xml | – sequence: 1 dbid: BNH name: ERIC url: http://search.epnet.com/ sourceTypes: Index Database |
| DeliveryMethod | fulltext_linktorsrc |
| Discipline | Education Chemistry |
| EISSN | 1938-1328 |
| ERIC | EJ1119661 |
| EndPage | 1934 |
| ExternalDocumentID | 4320817611 10_1021_acs_jchemed_6b00172 EJ1119661 c511099525 |
| GeographicLocations | Brazil |
| GeographicLocations_xml | – name: Brazil |
| GroupedDBID | .K2 02 53G 53T 55A 5D0 5GY 5VS 85S AABCJ AABXI AADNC AAIKC AAWRB AAWXH ABAMP ABDQB ABEFU ABFLS ABMVS ABOCM ABPPZ ABPTK ABUCX ABUFD ACCAO ACGFS ACGOD ACIWK ACNCT ACS AEESW AENEX AETEA AFEFF ALMA_UNASSIGNED_HOLDINGS AQSVZ BAANH CJ0 DU5 DZ E.L EBS ED ED~ EJD ET F20 F5P FA8 FH7 GNL JG JG~ K2 LG6 M0P P2P QJJ RNS ROL RWL RXW SJN TAE TN5 TWZ UCJ UHB UI2 UKR UPT VF5 VG9 VQA W1F WH7 X X7L XFK XHC XKZ XZL YCJ YZZ ZCG ZHY ZUP -DZ -ET -~X .GJ 0-V 0B8 186 29K 3EH 3O- 3V. 4.4 6TJ 7K8 7SW 7X7 88E 88I 8A4 8FE 8FG 8FH 8FI 8FJ 8G5 8R4 8R5 9M8 AAHBH AAMNW AAUTI AAYJJ AAYOK ABFSI ABJCF ABJNI ABQRX ABUWG ACGFO ACKIV ACKOT ACPVT ACQAM ACTDY ADBBV ADHLV ADMHC ADUKH AFFDN AFFNX AFKRA AFXLT AHGAQ AI. AIDAL AIKWM AIMQZ ALIPV ALSLI ARALO AZQEC BENPR BGLVJ BHPHI BJH BKOMP BKSAR BNH BNI BNJ BNO BPHCQ BVXVI CCPQU CJNVE CUPRZ CZ9 D-I D1I DWQXO D~A ERI FAC FAS FJW FYUFA GGK GNUQQ GUQSH HCIFZ HF~ HMCUK H~9 KB. KC. LIQON LK5 M1P M2O M2P M7R MVM NHB OHT P-O PADUT PCBAR PDBOC PET PQEDU PQQKQ PRG PROAC PSQYO Q2X QZG REK T9H UBC UKHRP UMD UQL USG VH1 WWN XJT XOL XSW YQT YRY YV5 YYP YYQ ZCA ZE2 ZGI ZKG ZXP ~02 AAYXX CITATION K9. |
| ID | FETCH-LOGICAL-a405t-6bfe94c466fc1823e5d8498b87b3957f7b917bfa09c409285cfcffe4390df2ef3 |
| IEDL.DBID | ACS |
| ISSN | 0021-9584 |
| IngestDate | Mon Nov 25 09:48:23 EST 2024 Thu Sep 26 19:08:32 EDT 2024 Fri Sep 06 12:18:21 EDT 2024 Thu Aug 27 13:42:43 EDT 2020 |
| IsDoiOpenAccess | false |
| IsOpenAccess | false |
| IsPeerReviewed | true |
| IsScholarly | true |
| Issue | 11 |
| Keywords | First-Year Undergraduate/General Hands-On Learning/Manipulatives Laboratory Instruction Colloids Interdisciplinary/Multidisciplinary High School/Introductory Chemistry Inquiry-Based/Discovery Learning Magnetic Properties Environmental Chemistry Nanotechnology |
| Language | English |
| LinkModel | DirectLink |
| MergedId | FETCHMERGED-LOGICAL-a405t-6bfe94c466fc1823e5d8498b87b3957f7b917bfa09c409285cfcffe4390df2ef3 |
| PQID | 1877711087 |
| PQPubID | 41672 |
| PageCount | 6 |
| ParticipantIDs | proquest_journals_1877711087 crossref_primary_10_1021_acs_jchemed_6b00172 eric_primary_EJ1119661 acs_journals_10_1021_acs_jchemed_6b00172 |
| ProviderPackageCode | JG~ 55A AABXI GNL VF5 XKZ VG9 W1F ACS AEESW AFEFF .K2 ABMVS ABUCX BAANH AQSVZ ED~ UI2 |
| PublicationCentury | 2000 |
| PublicationDate | 2016-11-08 |
| PublicationDateYYYYMMDD | 2016-11-08 |
| PublicationDate_xml | – month: 11 year: 2016 text: 2016-11-08 day: 08 |
| PublicationDecade | 2010 |
| PublicationPlace | Easton |
| PublicationPlace_xml | – name: Easton |
| PublicationTitle | Journal of chemical education |
| PublicationTitleAlternate | J. Chem. Educ |
| PublicationYear | 2016 |
| Publisher | American Chemical Society and Division of Chemical Education, Inc Division of Chemical Education, Inc and ACS Publications Division of the American Chemical Society American Chemical Society |
| Publisher_xml | – name: American Chemical Society and Division of Chemical Education, Inc – name: Division of Chemical Education, Inc and ACS Publications Division of the American Chemical Society – name: American Chemical Society |
| References | ref6/cit6 ref10/cit10 ref3/cit3 ref18/cit18 ref19/cit19 ref21/cit21 ref11/cit11 ref12/cit12 ref15/cit15 Toma H. E. (ref9/cit9) 2009 Vogel A. I. (ref20/cit20) 1968 ref22/cit22 ref13/cit13 ref14/cit14 ref8/cit8 Sparks D. L. (ref16/cit16) 2003 ref5/cit5 Aiken G. R. (ref17/cit17) 1985 ref2/cit2 ref4/cit4 ref1/cit1 ref7/cit7 |
| References_xml | – ident: ref3/cit3 doi: 10.1021/ed073p1183 – ident: ref2/cit2 doi: 10.1021/ed200150f – ident: ref8/cit8 doi: 10.1016/j.envpol.2010.03.024 – ident: ref18/cit18 doi: 10.1006/eesa.2000.1947 – ident: ref4/cit4 doi: 10.1021/ed079p715 – ident: ref10/cit10 doi: 10.1021/ed100010c – volume-title: Environmental Soil Chemistry year: 2003 ident: ref16/cit16 doi: 10.1016/B978-012656446-4/50001-3 contributor: fullname: Sparks D. L. – volume-title: Humic Substances in Soil, Sediment, and Water: Geochemistry, Isolation and Characterization year: 1985 ident: ref17/cit17 contributor: fullname: Aiken G. R. – ident: ref5/cit5 doi: 10.1016/j.envpol.2007.11.015 – ident: ref11/cit11 doi: 10.1021/ed500246s – volume-title: Quantitative Inorganic Analysis year: 1968 ident: ref20/cit20 contributor: fullname: Vogel A. I. – ident: ref21/cit21 doi: 10.1351/PAC-CON-12-12-02 – ident: ref15/cit15 doi: 10.1016/j.scitotenv.2013.09.044 – ident: ref19/cit19 doi: 10.1016/j.seppur.2005.12.022 – ident: ref7/cit7 doi: 10.1038/nature06599 – volume-title: O Mundo Nanométrico: A Dimensão do Novo Século year: 2009 ident: ref9/cit9 contributor: fullname: Toma H. E. – ident: ref1/cit1 doi: 10.1016/j.jclepro.2007.04.018 – ident: ref14/cit14 doi: 10.1016/0016-7037(80)90221-5 – ident: ref6/cit6 doi: 10.1016/j.jenvman.2010.11.011 – ident: ref22/cit22 doi: 10.1039/C5GC00066A – ident: ref13/cit13 doi: 10.1016/j.jmmm.2015.08.092 – ident: ref12/cit12 doi: 10.1016/j.jmmm.2006.05.001 |
| SSID | ssj0012598 |
| Score | 2.218431 |
| Snippet | A laboratory experiment has been developed to illustrate environmental and sustainability aspects, focusing on the wastewater treatment by means of... |
| SourceID | proquest crossref eric acs |
| SourceType | Aggregation Database Index Database Publisher |
| StartPage | 1929 |
| SubjectTerms | Ammonia Brazil Chemistry Contaminants Contamination Environmental Education Foreign Countries Green chemistry High School Students Humic acids Ions Laboratory Experiments Metal ions Metallurgy Nanoparticles Nanotechnology Organic chemistry Science Experiments Science Instruction Science Laboratories Secondary School Science Secondary school students Students Sustainability Sustainable development Wastewater treatment Water Pollution Water treatment |
| Title | Introducing Environmental and Sustainable Chemistry Topics Using a Nanotechnology Approach: Removing Hazardous Metal Ions by Means of Humic-Acid-Modified Superparamagnetic Nanoparticles |
| URI | http://dx.doi.org/10.1021/acs.jchemed.6b00172 http://eric.ed.gov/ERICWebPortal/detail?accno=EJ1119661 https://www.proquest.com/docview/1877711087 |
| Volume | 93 |
| hasFullText | 1 |
| inHoldings | 1 |
| isFullTextHit | |
| isPrint | |
| link | http://sdu.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwlV07T8MwELagDLDwKCAKBXlgYMAlTVwnYatKK6jUDhQktshPVKQmVdMO8M_4d5zzaEECBEskR9bZ0V3uvvM9jNA54y54_4ISA_iWUOFQIlqhIMK4zNW-snJkjy5G_vApuOnaNjnkhwi-27ziMm28wAeAcWiw3GdZRxuuD1jBIqHOaBk0ACSfK16bdQCGtWwy9D0Ra45k-sUcfc14LpVyZml6O__c4y7aLiAlbucysIfWdFxFm53yJreqvZm5yOLYR-93NjUdxmCycHdV5QYEeKzwaFVPhZcU8EMyHcsUZ-kFmGPQyMl8eSSP20Vb8mt8ryfZAQW-5W8geckixQNtSd-BbGPxCiOwjDgxGKRoLElbjhUZJGpsAAjD2lM9s63IJ_w5trWV2ULTMnXvAD32ug-dW1Jc30A4oMA5YcLokErKmJHgxXi6pQIaBiLwhQ0OGl-AqygMd0IJTqYbtKSRxmhASI4yrjbeIarESayPEA4pNQCUQHMLRT2tOPe4aGnlNRlzROjU0AWwICp-vzTKIutuM8pe5nyJCr7U0GXJ8GiaN_T4ffqhFYrl1G4fjAO4iM0aqpdi8mld213RFlb4x3_f0QnaAhTGsgLHoI4q89lCn6L1VC3OMvmG56g__ACEf_wL |
| link.rule.ids | 315,782,786,2769,27085,27933,27934,56747,56797 |
| linkProvider | American Chemical Society |
| linkToHtml | http://sdu.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV07b9swED407pAsfeSBOHVbDhk6lIksUZTUzXAd2E2coXaAbAKfgQtEMiJ7SP9Z_12PlGQ3QBEUHUkQRwp3uvuO9yDAKRchev-SUYv4ljIZMCrjTFJpQx6aRDs5clcXs-T6Nv06cm1yWFsLg4eokFLlg_jb7gL9czf3A78DbcQZr12XHXgZc4TDDhANZ5vYAQL6Wv-65AO0r22vob8TcVZJVU-s0tPE51Y3e4Nz8fr_jvoGXjUAkwxqiXgLL0yxD7vD9l23ffdOc5PTcQC_Ji5RHcdowMhoW_OGBEShyWxbXUU2FMi8XC5URXyyAREE9XO52lzQk0HTpPwL-W7u_XUFGYufKIfluiJT40hPUNKJfMQR2klSWoIytVB0oBaaTku9sAiLce-leXCNye_FXeEqLf1GyzaR7xBuLkbz4Zg2jzlQgZhwRbm0JmOKcW4V-jSRiXXKslSmiXShQptIdBylFUGm0OUM01hZZa1BvBRoGxobHUGnKAtzDCRjzCJsQj0uNYuMFiISMjY66nMeyCzowidkQd78jFXu4-xhP_eTNV_yhi9d-NzyPV_W7T2eX37kZGOzdPQNTQU6jP0u9Fpp-WNf12vRlVkkJ_9-oo-wO55Pr_KryfXlO9hDfMZ96WPag87qYW3ew06l1x-8yP8GBKUDew |
| linkToPdf | http://sdu.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV1Lb9QwEB7RIgGXAoWKLQV84MABQzZxnITbarurLtAKsUXiFvlZLVKTqNk9wD_j3zHjJFsqIYQ4xrLGjubzPDwPA7yUKkbvXwvu0b7lQkeC67TQXPtYxi6zhCO6ulhmZ1_z4xm1ycmHWhjcRIuU2hDEp1PdWN93GBi_pfFv-C-oJ97Izn3ZgdupzApyuybT5TZ-gEZ9J4MpAQF17NBv6M9ESDOZ9oZmupn8PMjnoHTm9_9_uw9grzc02aRDxkO45ap9uDsd3nfbp_ea-9yOR_BzQQnr-I2KjM2ua9-QgKosW15XWbEtBXZeNyvTspB0wBRDOV2vtxf1bNI3K3_HPrvLcG3BTtQPxGO9admpI9ILRDzT3_EL9SWrPUNsrQyfmJXlp7VdeTSPce3GXVGD8kt1UVHFZVioGRL6HsOX-ex8esL7Rx24QttwzaX2rhBGSOkN-jaJS20uilznmaaQoc80OpDaq6gw6HrGeWq88d6h3RRZHzufHMBuVVfuCbBCCI_mE8pzbUXirFKJ0qmzyVjKSBfRCF4hC8r-ULZliLfH4zIMdnwpe76M4PXA-7Lp2nz8ffoB4WM7dfYeVQY6juMRHA2I-W1d6rlI5RbZ4b_v6AXc-XQ8Lz8uzj48hXtopslQAZkfwe76auOewU5rN88D6n8BUFgF_g |
| openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Introducing+Environmental+and+Sustainable+Chemistry+Topics+Using+a+Nanotechnology+Approach%3A+Removing+Hazardous+Metal+Ions+by+Means+of+Humic-Acid-Modified+Superparamagnetic+Nanoparticles&rft.jtitle=Journal+of+chemical+education&rft.au=da+Silva%2C+Delm%C3%A1rcio+Gomes&rft.au=de+Melo%2C+Fernando+Menegatti&rft.au=Silveira%2C+Alceu+Totti&rft.au=da+Cruz%2C+Bruno+Constancio&rft.date=2016-11-08&rft.pub=American+Chemical+Society&rft.issn=0021-9584&rft.eissn=1938-1328&rft.volume=93&rft.issue=11&rft.spage=1929&rft_id=info:doi/10.1021%2Facs.jchemed.6b00172&rft.externalDBID=NO_FULL_TEXT&rft.externalDocID=4320817611 |
| thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=0021-9584&client=summon |
| thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=0021-9584&client=summon |
| thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=0021-9584&client=summon |