Tandem [3,3]-Sigmatropic Rearrangements in an Ansamycin: Stereospecific Conversion of an (S)-Allylic Alcohol to an (S)-Allylic Amine Derivative

Tandem [3,3]-Sigmatropic Rearrangements in an Ansamycin: Stereospecific Conversion of an (S)-Allylic Alcohol to an (S)-Allylic Amine Derivative

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Bibliographic Details
Published in:Journal of organic chemistry Vol. 59; no. 9; pp. 2581 - 2584
Main Authors: Schnur, Rodney C, Corman, Michael L
Format: Journal Article
Language:English
Published: Washington, DC American Chemical Society 01-05-1994
Subjects:
Chemistry
Exact sciences and technology
Heterocyclic compounds
Heterocyclic compounds with only one n hetero atom and condensed derivatives
Organic chemistry
Preparations and properties
Sigmatropic reaction
Chemical rearrangement
Nitrogen heterocycle
Azetidine derivatives
Quinone
Configuration retention
Lactam
Alcohol
Stereospecificity
Tandem reaction
Thioureas
Macrocycle
Online Access:Get full text
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Description
Bibliography:ark:/67375/TPS-4NWKGFLK-S
istex:3B3485E2AEA0A23FE6BD42B55DF8FDDA27E048C0
ISSN:0022-3263
1520-6904
DOI:10.1021/jo00088a047