Preparation, solution structures, and nucleophilic reactions of chiral, bimetallic complexes: [(.mu.-.eta.2,.eta.3-propargylium)Co2(CO)5P(C6H5)3]BF4

Preparation, solution structures, and nucleophilic reactions of chiral, bimetallic complexes: [(.mu.-.eta.2,.eta.3-propargylium)Co2(CO)5P(C6H5)3]BF4

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Bibliographic Details
Published in:Organometallics Vol. 11; no. 7; pp. 2598 - 2607
Main Authors: Bradley, David H, Khan, Masood A, Nicholas, Kenneth M
Format: Journal Article
Language:English
Published: Washington, DC American Chemical Society 01-07-1992
Subjects:
Chemistry
Condensed matter: structure, mechanical and thermal properties
Exact sciences and technology
Organic chemistry
Organic compounds
Organometalloidal and organometallic compounds
Physics
Preparations and properties
Structure of solids and liquids; crystallography
Structure of specific crystalline solids
Transition metals derivatives
Acetylenic compound
Tertiary phosphine
Cobalt Carbonyl Complexes
Organic ligand
Transition metal Carbonyl Complexes
Cis trans isomerization
Diastereoselectivity
Carbene
Cobalt Organic compounds
Mu complex
Trapping
Metal metal bond
Dinuclear complex
Reaction mechanism
Hapto complex
Kinetics
Methanol
Nucleophile
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Description
Bibliography:ark:/67375/TPS-76X57LH5-0
istex:083C1E7CAC675DAAEB1E9230F4B5A5578B46380D
ISSN:0276-7333
1520-6041
DOI:10.1021/om00043a050