CO Desorption from a Catalytic Surface: Elucidation of the Role of Steps by Velocity-Selected Residence Time Measurements

Directly measuring the rate of a surface chemical reaction remains a challenging problem. For example, even after more than 30 years of study, there is still no agreement on the kinetic parameters for one of the simplest surface reactions: desorption of CO from Pt(111). We present a new experimental...

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Bibliographic Details

Published in:	Journal of the American Chemical Society Vol. 137; no. 4; pp. 1465 - 1475
Main Authors:	Golibrzuch, Kai, Shirhatti, Pranav R, Geweke, Jan, Werdecker, Jörn, Kandratsenka, Alexander, Auerbach, Daniel J, Wodtke, Alec M, Bartels, Christof
Format:	Journal Article
Language:	English
Published:	United States American Chemical Society 04-02-2015
Subjects:	Adsorption Carbon Monoxide - isolation & purification Catalysis Kinetics Models, Molecular Platinum - chemistry Spectrum Analysis - instrumentation Surface Properties Thermodynamics Ultraviolet Rays
Online Access:	Get full text
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