Diastereoselective Addition of Allyltitanocenes to Cyclic Enones
The reaction of allyltitanocenes with five- to seven-membered cyclic enones proceeded with good to high diastereoselectivity depending on the ring size of enones. The stereochemistry of the major isomers produced by the reaction of cinnamyltitanocene was opposite to that of crotyltitanocene.
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| Published in: | Organic letters Vol. 14; no. 8; pp. 2042 - 2045 |
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| Main Authors: | , , , , , |
| Format: | Journal Article |
| Language: | English |
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United States
American Chemical Society
20-04-2012
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| Abstract | The reaction of allyltitanocenes with five- to seven-membered cyclic enones proceeded with good to high diastereoselectivity depending on the ring size of enones. The stereochemistry of the major isomers produced by the reaction of cinnamyltitanocene was opposite to that of crotyltitanocene. |
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| AbstractList | The reaction of allyltitanocenes with five- to seven-membered cyclic enones proceeded with good to high diastereoselectivity depending on the ring size of enones. The stereochemistry of the major isomers produced by the reaction of cinnamyltitanocene was opposite to that of crotyltitanocene. |
| Author | Yoshida, Satoshi Tsubouchi, Akira Takeda, Takeshi Tajima, Yuki Nishimura, Takuya Saiki, Fumiya |
| Author_xml | – sequence: 1 givenname: Takeshi surname: Takeda fullname: Takeda, Takeshi email: takeda-t@cc.tuat.ac.jp – sequence: 2 givenname: Takuya surname: Nishimura fullname: Nishimura, Takuya – sequence: 3 givenname: Satoshi surname: Yoshida fullname: Yoshida, Satoshi – sequence: 4 givenname: Fumiya surname: Saiki fullname: Saiki, Fumiya – sequence: 5 givenname: Yuki surname: Tajima fullname: Tajima, Yuki – sequence: 6 givenname: Akira surname: Tsubouchi fullname: Tsubouchi, Akira |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/22472169$$D View this record in MEDLINE/PubMed |
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| CitedBy_id | crossref_primary_10_1002_anie_201202808 crossref_primary_10_5059_yukigoseikyokaishi_71_98 crossref_primary_10_1016_j_tetlet_2015_04_114 crossref_primary_10_1021_ol401055m crossref_primary_10_1002_chem_201304775 crossref_primary_10_1039_c3cc41826j crossref_primary_10_1021_acs_organomet_7b00765 crossref_primary_10_1002_ange_201202808 crossref_primary_10_1002_chin_201233062 crossref_primary_10_1021_acs_orglett_5b00084 |
| Cites_doi | 10.1002/anie.200700975 10.1021/jo9723016 10.1021/ja910593w 10.1002/anie.200901384 10.1002/cber.19901230127 10.1002/anie.200603659 10.1021/ja062528v 10.1021/ja071380s 10.1002/anie.201003813 10.1021/ja0274047 10.1246/cl.1980.993 10.1002/chem.201000101 10.1002/chem.200802340 10.1016/j.tet.2011.10.002 10.1021/ja804182j 10.1016/S0040-4039(99)01982-6 10.1021/ja047200l 10.1021/ol900599q 10.1021/ol702607t |
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| Title | Diastereoselective Addition of Allyltitanocenes to Cyclic Enones |
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