Photoinduced Smart, Self-Healing Polymer Sealant for Photovoltaics
Polyisobutylene (PIB)-based polymer networks potentially useful as smart coatings for photovoltaic devices have been developed. Low molecular weight coumarin functional triarm star PIB was synthesized via a single step SN2 reaction of bromoallyl functional triarm star PIB with 4-methylumbelliferone...
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| Published in: | ACS applied materials & interfaces Vol. 7; no. 3; pp. 2064 - 2072 |
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| Main Authors: | , , , , , , |
| Format: | Journal Article |
| Language: | English |
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American Chemical Society
28-01-2015
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| Abstract | Polyisobutylene (PIB)-based polymer networks potentially useful as smart coatings for photovoltaic devices have been developed. Low molecular weight coumarin functional triarm star PIB was synthesized via a single step SN2 reaction of bromoallyl functional triarm star PIB with 4-methylumbelliferone or umbelliferone in the presence of sodium hydride. Quantitative end functionality was confirmed by matrix-assisted laser desorption/ionization time-of-flight mass spectrometry. UVA (λmax = 365 nm) induced reversible photodimerization of the coumarin moieties resulted in cross-linked elastomeric films exhibiting self-healing behavior. The extent of photodimerization/photoscission was monitored by UV–vis spectroscopy. The low oxygen (1.9 × 10–16 mol m m–2 s–1 Pa–1) and moisture (46 × 10–16 mol m m–2 s–1 Pa–1) permeability of the cross-linked polymer films suggest excellent barrier properties of the cross-linked polymer films. The self-healing process was studied by atomic force microscopy (AFM). For this, mechanical cuts were introduced in the cross-linked PIB films through micromachining with an AFM tip and the rate of healing induced by UV, sunlight, or both was followed by taking AFM images of the film at different time intervals during the repair process. |
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| AbstractList | Polyisobutylene (PIB)-based polymer networks potentially useful as smart coatings for photovoltaic devices have been developed. Low molecular weight coumarin functional triarm star PIB was synthesized via a single step SN2 reaction of bromoallyl functional triarm star PIB with 4-methylumbelliferone or umbelliferone in the presence of sodium hydride. Quantitative end functionality was confirmed by matrix-assisted laser desorption/ionization time-of-flight mass spectrometry. UVA (λmax = 365 nm) induced reversible photodimerization of the coumarin moieties resulted in cross-linked elastomeric films exhibiting self-healing behavior. The extent of photodimerization/photoscission was monitored by UV-vis spectroscopy. The low oxygen (1.9 × 10(-16) mol m m(-2) s(-1) Pa(-1)) and moisture (46 × 10(-16) mol m m(-2) s(-1) Pa(-1)) permeability of the cross-linked polymer films suggest excellent barrier properties of the cross-linked polymer films. The self-healing process was studied by atomic force microscopy (AFM). For this, mechanical cuts were introduced in the cross-linked PIB films through micromachining with an AFM tip and the rate of healing induced by UV, sunlight, or both was followed by taking AFM images of the film at different time intervals during the repair process. |
| Author | Nagy, Tibor Cozzens, David Keki, Sandor Zsuga, Miklos Faust, Rudolf Tripathy, Ranjan Banerjee, Sanjib |
| AuthorAffiliation | Department of Chemistry University of Massachusetts Lowell University of Debrecen Department of Applied Chemistry |
| AuthorAffiliation_xml | – name: Department of Applied Chemistry – name: Department of Chemistry – name: University of Debrecen – name: University of Massachusetts Lowell |
| Author_xml | – sequence: 1 givenname: Sanjib surname: Banerjee fullname: Banerjee, Sanjib organization: University of Massachusetts Lowell – sequence: 2 givenname: Ranjan surname: Tripathy fullname: Tripathy, Ranjan organization: University of Massachusetts Lowell – sequence: 3 givenname: David surname: Cozzens fullname: Cozzens, David organization: University of Massachusetts Lowell – sequence: 4 givenname: Tibor surname: Nagy fullname: Nagy, Tibor organization: University of Debrecen – sequence: 5 givenname: Sandor surname: Keki fullname: Keki, Sandor organization: University of Debrecen – sequence: 6 givenname: Miklos surname: Zsuga fullname: Zsuga, Miklos organization: University of Debrecen – sequence: 7 givenname: Rudolf surname: Faust fullname: Faust, Rudolf email: Rudolf_Faust@uml.edu organization: University of Massachusetts Lowell |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/25545670$$D View this record in MEDLINE/PubMed |
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| Keywords | photovoltaic devices polyisobutylene functional coatings photochemistry self-healing |
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| Snippet | Polyisobutylene (PIB)-based polymer networks potentially useful as smart coatings for photovoltaic devices have been developed. Low molecular weight coumarin... |
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| Title | Photoinduced Smart, Self-Healing Polymer Sealant for Photovoltaics |
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