Reverse-Micelle Formation in the Partitioning of Trivalent f-Element Cations by Biphasic Systems Containing a Tetraalkyldiglycolamide

The conditions for reverse-micelle formation were studied for solutions of tetra-n-octyldiglycolamide (TODGA) in alkane diluents equilibrated with aqueous solutions of nitric or hydrochloric acids in the presence and absence of Nd3+. Small-angle neutron scattering, vapor-pressure osmometry, and tens...

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Bibliographic Details
Published in:	Langmuir Vol. 23; no. 9; pp. 4765 - 4774
Main Authors:	Jensen, Mark P, Yaita, Tsuyoshi, Chiarizia, Renato
Format:	Journal Article
Language:	English
Published:	Washington, DC American Chemical Society 24-04-2007
Subjects:	Cations - chemistry Chemistry Colloidal state and disperse state Exact sciences and technology General and physical chemistry Glycolates - chemistry Hydrochloric Acid - chemistry Micelles Micelles. Thin films Molecular Structure Neodymium - chemistry Neutron Diffraction Nitric Acid - chemistry Physical and chemical studies. Granulometry. Electrokinetic phenomena Scattering, Small Angle Solutions - chemistry Water - chemistry Diluent Attraction Lanthanide Hydrocarbon Vapor pressure Acidity Nitric acid Hydrochloric acid Biphasic system Acids Small angle neutron scattering Alkane Affinity Trivalent cation Dimer Extraction Models Osmometry Polydispersed particle Aqueous solution Thermodynamic properties Reverse micelle Monomer
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