Molecular Dyads of Ruthenium(II)– or Osmium(II)–Bis(terpyridine) Chromophores and Expanded Pyridinium Acceptors: Equilibration between MLCT and Charge-Separated Excited States

The synthesis, characterization, redox behavior, and photophysical properties (both at room temperature in fluid solution and at 77 K in rigid matrix) of a series of four new molecular dyads (2–5) containing Ru(II)– or Os(II)–bis(terpyridine) subunits as chromophores and various expanded pyridinium...

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Published in:	Inorganic chemistry Vol. 52; no. 20; pp. 11944 - 11955
Main Authors:	Fortage, Jérôme, Dupeyre, Grégory, Tuyèras, Fabien, Marvaud, Valérie, Ochsenbein, Philippe, Ciofini, Ilaria, Hromadová, Magdaléna, Pospísil, Lubomír, Arrigo, Antonino, Trovato, Emanuela, Puntoriero, Fausto, Lainé, Philippe P, Campagna, Sebastiano
Format:	Journal Article
Language:	English
Published:	United States American Chemical Society 21-10-2013
Online Access:	Get full text
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