Two Polymerizable Derivatives of 2,2‘-Azino-bis(3-ethylbenzthiazoline-6-sulfonic acid)

Two Polymerizable Derivatives of 2,2‘-Azino-bis(3-ethylbenzthiazoline-6-sulfonic acid)

A versatile strategy for the synthesis of polymerizable derivatives of the redox-active indicator dye 2,2‘-azino-bis(3-ethylbenzthiazoline-6-sulfonic acid) (ABTS) is reported. Two products are shown to illustrate how the final step in the synthetic strategy can be used to alter the physical properti...

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Bibliographic Details
Published in:Organic letters Vol. 8; no. 1; pp. 3 - 6
Main Authors: Fei, Jiangfeng, Basu, Amit, Xue, Fengtian, Palmore, G. Tayhas R
Format: Journal Article
Language:English
Published: United States American Chemical Society 05-01-2006
Online Access:Get full text
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Summary:A versatile strategy for the synthesis of polymerizable derivatives of the redox-active indicator dye 2,2‘-azino-bis(3-ethylbenzthiazoline-6-sulfonic acid) (ABTS) is reported. Two products are shown to illustrate how the final step in the synthetic strategy can be used to alter the physical properties of the product. Both products were characterized spectroscopically and electrochemically. The hydrophilic monomer (sABTS) was polymerized, and the utility of this polymer (polyABTS) is demonstrated in the context of bioelectrocatalysis.
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ISSN:1523-7060
1523-7052
DOI:10.1021/ol0513443