Measurement of Diffusion of Atmospheric Gases in a Liquid Perfluoro Compound by Means of an Optical Technique

• Published in: The journal of physical chemistry. B Vol. 127; no. 15; pp. 3584 - 3595
• Main Authors: Mialdun, Aliaksandr, Yasnou, Viktar, Barakhovskaia, Ella, Glushchuk, Andrey, Shevtsova, Valentina
• Format: Journal Article
• Language: English
• Published: United States American Chemical Society 20-04-2023
• Subjects: B: Soft Matter, Fluid Interfaces, Colloids, Polymers, and Glassy Materials
• ISSN: 1520-6106; 1520-5207
• DOI: 10.1021/acs.jpcb.3c01524

We report on accurate measurements of Fickian diffusion coefficients in binary mixtures consisting of hydrofluoroether (a perfluoro compound of methoxy-nonafluoro­butane or HFE-7100) with dissolved atmospheric gases CO2, N2, and O2 in the limit of an infinite dilution of the gas. We show that the use of optical digital interferometry (ODI) allows the determination of diffusion coefficients of dissolved gases with relatively small standard uncertainties for this class of experiments. In addition, we illustrate the ability of an optical approach to determine the gas concentration. We compare the capacity of four mathematical models, singly used in the literature, to obtain diffusion coefficients by applying them to the processing of a large amount of experimental data. We quantify their systematic errors and standard uncertainties. The temperature behavior of the diffusion coefficients measured in the range of 10 to 40 °C is consistent with the behavior of the same gases in other solvents available in the literature.