Trinuclear Clusters of Ruthenium-Containing Bridging and Ortho-Metalated 2,2‘-Bis(diphenylphosphino)-1,1‘-binaphthyl (BINAP): X-ray Structures of (R)-BINAP and [Ru3(μ-OH)2(CO)8{μ-(R)-BINAP}]
The cluster [Ru3(CO)12] normally reacts readily with tertiary phosphines and diphosphines in the presence of Me3NO to give simple phosphine-substituted derivatives by a reaction involving nucleophilic attack of the amine oxide at CO leading to CO2 formation. However, the corresponding reaction of [R...
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| Published in: | Organometallics Vol. 16; no. 26; pp. 6004 - 6009 |
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| Main Authors: | , , |
| Format: | Journal Article |
| Language: | English |
| Published: |
American Chemical Society
23-12-1997
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| Online Access: | Get full text |
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