Electron Delocalization Mediates the Metal-Dependent Capacity for CH/π Interactions of Acetylacetonato Chelates

CH/π interactions between the coordinated acetylacetonato ligand and phenyl rings were analyzed in the crystal structures from the Cambridge Structural Database and by quantum chemical calculations. The acetylacetonato ligand may engage in two types of interactions:  it can be hydrogen atom donor or...

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Bibliographic Details

Published in:	Inorganic chemistry Vol. 45; no. 12; pp. 4755 - 4763
Main Authors:	Milčič, Miloš K, Medaković, Vesna B, Sredojević, Dušan N, Juranić, Nenad O, Zarić, Snežana D
Format:	Journal Article
Language:	English
Published:	United States American Chemical Society 12-06-2006
Online Access:	Get full text
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