High-Yield Formation of Giant Bis(bicyclic) and Crypt-tris(bicyclic) Molecules under Normal Reaction Conditions
We report the unexpected result of the reaction of 1,3-bis[(9-anthrylmethoxy)methyl]benzene (1a) or 1,3,5-tris[(9-anthrylmethoxy)methyl]benzene (1b) with tris(2-maleimidoethyl)amine (2) in homogeneous solution leading to giant bis(bicyclic) and crypt-tris(bicyclic) molecules. The anticipated, intrac...
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| Published in: | Journal of organic chemistry Vol. 65; no. 13; pp. 3941 - 3946 |
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| Main Authors: | , , , , |
| Format: | Journal Article |
| Language: | English |
| Published: |
United States
American Chemical Society
30-06-2000
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| Online Access: | Get full text |
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| Summary: | We report the unexpected result of the reaction of 1,3-bis[(9-anthrylmethoxy)methyl]benzene (1a) or 1,3,5-tris[(9-anthrylmethoxy)methyl]benzene (1b) with tris(2-maleimidoethyl)amine (2) in homogeneous solution leading to giant bis(bicyclic) and crypt-tris(bicyclic) molecules. The anticipated, intractable solids are obtained in a condensed state reaction using an oscillating mill. |
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| Bibliography: | istex:6DCCF59B17A74A74BC6393EB15BF70B0B3CBB13A ark:/67375/TPS-01BDPBQ3-6 ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
| ISSN: | 0022-3263 1520-6904 |
| DOI: | 10.1021/jo991783d |