Uncommon Ferromagnetic Interactions in a Homometallic Co(II) Chain Bridged by a Single End-to-End Azide

Uncommon Ferromagnetic Interactions in a Homometallic Co(II) Chain Bridged by a Single End-to-End Azide

A new one-dimensional heterochiral coordination polymer [Co(bmdt)(N3)2]·MeCN (1·MeCN) with well-isolated chains was prepared via a self-assembly process. Magnetic data show that intrachain ferromagnetic couplings via the single end-to-end azide group are observed, which is an extraordinary case amon...

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Bibliographic Details
Published in:Inorganic chemistry Vol. 46; no. 22; pp. 9054 - 9056
Main Authors: Yoo, Houng Sik, Kim, Jae Il, Yang, Namgeun, Koh, Eui Kwan, Park, Je-Geun, Hong, Chang Seop
Format: Journal Article
Language:English
Published: United States American Chemical Society 29-10-2007
Subjects:
Azides - chemistry
Copper - chemistry
Iron - chemistry
Magnetics
Models, Molecular
Online Access:Get full text
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Summary:A new one-dimensional heterochiral coordination polymer [Co(bmdt)(N3)2]·MeCN (1·MeCN) with well-isolated chains was prepared via a self-assembly process. Magnetic data show that intrachain ferromagnetic couplings via the single end-to-end azide group are observed, which is an extraordinary case among the azide-bridged Co(II) systems.
Bibliography:ark:/67375/TPS-XT3948HS-7
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ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:0020-1669
1520-510X
DOI:10.1021/ic7014995