Conformational Changes of a Calix[8]arene Derivative at the Air−Water Interface

• Published in: The journal of physical chemistry. B Vol. 109; no. 9; pp. 3998 - 4006
• Main Authors: de Miguel, Gustavo, Pedrosa, José M, Martín-Romero, María T, Muñoz, Eulogia, Richardson, Tim H, Camacho, Luis
• Format: Journal Article
• Language: English
• Published: United States American Chemical Society 10-03-2005
• ISSN: 1520-6106; 1520-5207
• DOI: 10.1021/jp045857n

The particular behavior of a p-tert-butyl calix[8]arene derivative (C8A) has been studied at the air−water interface using surface pressure−area isotherms, surface potential−area isotherms, film relaxation measurements, Brewster angle microscopy (BAM), and infrared spectroscopy for Langmuir−Blodgett films. Thus, it is observed that the properties of the film, for example, isotherms, domain formation, and FTIR spectra, recorded during the first compression cycle differ appreciably from those during the second compression and following cycles. The results obtained are interpreted on the basis of the conformational changes of the C8A molecules by surface pressure, allowing us to inquire into the inter- and intramolecular interactions (hydrogen bonds) of those molecules. Thus, the compression induces changes in the kind of hydrogen bonds from intra- and intermolecular with other C8A molecules to hydrogen bonds with water molecules.