An Efficient Catalyst for Pd-Catalyzed Carbonylation of Aryl Arenesulfonates
Aryl carboxylic esters were synthesized by Pd-catalyzed carbonylation of aryl p-fluorobenzenesulfonates or -tosylates. A unique Josiphos ligand was discovered through high-throughput catalyst screening, which was the key for the successful carbonylation of various substrates. This catalyst is effect...
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| Published in: | Organic letters Vol. 8; no. 22; pp. 5161 - 5164 |
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| Main Authors: | , , , , , , |
| Format: | Journal Article |
| Language: | English |
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American Chemical Society
26-10-2006
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| Abstract | Aryl carboxylic esters were synthesized by Pd-catalyzed carbonylation of aryl p-fluorobenzenesulfonates or -tosylates. A unique Josiphos ligand was discovered through high-throughput catalyst screening, which was the key for the successful carbonylation of various substrates. This catalyst is effective and works well for both electron-rich and electron-poor aryl arenesulfonates. Isolated yields of up to 90% were obtained for aryl p-fluorobenzenesulfonates and -tosylates. |
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| AbstractList | Aryl carboxylic esters were synthesized by Pd-catalyzed carbonylation of aryl p-fluorobenzenesulfonates or -tosylates. A unique Josiphos ligand was discovered through high-throughput catalyst screening, which was the key for the successful carbonylation of various substrates. This catalyst is effective and works well for both electron-rich and electron-poor aryl arenesulfonates. Isolated yields of up to 90% were obtained for aryl p-fluorobenzenesulfonates and -tosylates. Aryl carboxylic esters were synthesized by Pd-catalyzed carbonylation of aryl p-fluorobenzenesulfonates or -tosylates. A unique Josiphos ligand was discovered through high-throughput catalyst screening, which was the key for the successful carbonylation of various substrates. This catalyst is effective and works well for both electron-rich and electron-poor aryl arenesulfonates. Isolated yields of up to 90% were obtained for aryl p-fluorobenzenesulfonates and -tosylates. [reaction: see text] |
| Author | Shultz, C. Scott Cai, Chaoxian Balsells, Jaume Sidler, Rick R Sun, Yongkui Rivera, Nelo R McWilliams, J. Christopher |
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| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/17048868$$D View this record in MEDLINE/PubMed |
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| Snippet | Aryl carboxylic esters were synthesized by Pd-catalyzed carbonylation of aryl p-fluorobenzenesulfonates or -tosylates. A unique Josiphos ligand was discovered... |
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| SubjectTerms | Arylsulfonates - chemistry Catalysis Combinatorial Chemistry Techniques Esters Hydrocarbons, Fluorinated - chemistry Molecular Structure Palladium Tosyl Compounds - chemistry |
| Title | An Efficient Catalyst for Pd-Catalyzed Carbonylation of Aryl Arenesulfonates |
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