Vinyl Carbocations:  Solution Studies of Alkenyl(aryl)iodonium Triflate Fragmentations

Generation of vinyl cations is facile by fragmentation of alkenyl(aryl)iodonium trifluoromethanesulfonates. Kinetics and electronic effects were probed by 1H NMR spectroscopy in CDCl3. Products of fragmentation include six enol triflate isomers in addition to iodoarenes. The enol triflates arise fro...

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Bibliographic Details

Published in:	Journal of organic chemistry Vol. 66; no. 16; pp. 5556 - 5565
Main Authors:	McNeil, Anne J, Hinkle, Robert J, Rouse, E. Ashley, Thomas, Quinn A, Thomas, David B
Format:	Journal Article
Language:	English
Published:	United States American Chemical Society 10-08-2001
Online Access:	Get full text
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