Double [4]Helicene-like Naphthobisbenzothiophene Diimides and Their Thienyl-S,S-dioxidized Derivatives with Attractive Solid-State Fluorescence and High Electron Affinity

Double [4]Helicene-like Naphthobisbenzothiophene Diimides and Their Thienyl-S,S-dioxidized Derivatives with Attractive Solid-State Fluorescence and High Electron Affinity

A series of double [4]­helicene-like naphthobisbenzothiophene diimides and their thienyl-S,S-dioxidized derivatives are synthesized via MoCl5-catalyzed cyclization and m-CPBA-mediated oxidation reactions. The functional five-membered ring diimides show a helicene-like geometry, strong solid-state fl...

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Published in:Organic letters Vol. 25; no. 6; pp. 972 - 976
Main Authors: Yi, Xingyu, Gao, Junxiang, Qin, Hanwen, Zheng, Liping, Zeng, Weixuan, Chen, Huajie
Format: Journal Article
Language:English
Published: United States American Chemical Society 17-02-2023
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Abstract A series of double [4]­helicene-like naphthobisbenzothiophene diimides and their thienyl-S,S-dioxidized derivatives are synthesized via MoCl5-catalyzed cyclization and m-CPBA-mediated oxidation reactions. The functional five-membered ring diimides show a helicene-like geometry, strong solid-state fluorescence, and deep LUMO of −4.37 eV.
AbstractList A series of double [4]helicene-like naphthobisbenzothiophene diimides and their thienyl-S,S-dioxidized derivatives are synthesized via MoCl -catalyzed cyclization and -CPBA-mediated oxidation reactions. The functional five-membered ring diimides show a helicene-like geometry, strong solid-state fluorescence, and deep LUMO of -4.37 eV.
A series of double [4]­helicene-like naphthobisbenzothiophene diimides and their thienyl-S,S-dioxidized derivatives are synthesized via MoCl5-catalyzed cyclization and m-CPBA-mediated oxidation reactions. The functional five-membered ring diimides show a helicene-like geometry, strong solid-state fluorescence, and deep LUMO of −4.37 eV.
Author Yi, Xingyu
Gao, Junxiang
Chen, Huajie
Qin, Hanwen
Zeng, Weixuan
Zheng, Liping
AuthorAffiliation Department of Chemistry
Key Laboratory of Environmentally Friendly Chemistry and Applications of Ministry of Education, College of Chemistry
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BackLink https://www.ncbi.nlm.nih.gov/pubmed/36732283$$D View this record in MEDLINE/PubMed
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Snippet A series of double [4]­helicene-like naphthobisbenzothiophene diimides and their thienyl-S,S-dioxidized derivatives are synthesized via MoCl5-catalyzed...
A series of double [4]helicene-like naphthobisbenzothiophene diimides and their thienyl-S,S-dioxidized derivatives are synthesized via MoCl -catalyzed...
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Title Double [4]Helicene-like Naphthobisbenzothiophene Diimides and Their Thienyl-S,S-dioxidized Derivatives with Attractive Solid-State Fluorescence and High Electron Affinity
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