Anion/Naphthalenediimide Interactions in a Pd(II)-Based Tetrameric Metallocycle

A tetrameric metallocycle [Pd(dppp)(DPNDI)]4·8TfO consisting of four dppp-capped Pd(II) corners (dppp = 1,3-bis(diphenylphosphonium)propane) and four linear π-acidic N,N′-di(4-pyridyl)-1,4,5,8-naphthalene diimine (DPNDI) ligands has been synthesized, and its single-crystal structure has been...

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Published in:	Crystal growth & design Vol. 19; no. 11; pp. 6017 - 6022
Main Authors:	Gordillo, Monica A, Benavides, Paola A, Saha, Sourav
Format:	Journal Article
Language:	English
Published:	American Chemical Society 06-11-2019
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Abstract	A tetrameric metallocycle [Pd(dppp)(DPNDI)]4·8TfO consisting of four dppp-capped Pd(II) corners (dppp = 1,3-bis(diphenylphosphonium)propane) and four linear π-acidic N,N′-di(4-pyridyl)-1,4,5,8-naphthalene diimine (DPNDI) ligands has been synthesized, and its single-crystal structure has been elucidated for the first time. The crystal structure of the metallocycle revealed anion−π, lone-pair−π, and CH···anion interactions between electron-deficient DPNDI ligands and TfO– counterions and provided valuable insights into its anion recognition and metathesis capabilities. The 1H, 19F, and 31P NMR studies demonstrated that in noncoordinating solvents, such as nitromethane and dichloromethane, the [Pd(dppp)(DPNDI)]4 8+ metallocycle underwent anion exchange in a single-crystal to single-crystal fashion without any structural changes. However, the metallocycle experienced slow dissociation in a polar solvent DMSO, which could be reversed easily by thermal treatment.
AbstractList	A tetrameric metallocycle [Pd(dppp)(DPNDI)]4·8TfO consisting of four dppp-capped Pd(II) corners (dppp = 1,3-bis(diphenylphosphonium)propane) and four linear π-acidic N,N′-di(4-pyridyl)-1,4,5,8-naphthalene diimine (DPNDI) ligands has been synthesized, and its single-crystal structure has been elucidated for the first time. The crystal structure of the metallocycle revealed anion−π, lone-pair−π, and CH···anion interactions between electron-deficient DPNDI ligands and TfO– counterions and provided valuable insights into its anion recognition and metathesis capabilities. The 1H, 19F, and 31P NMR studies demonstrated that in noncoordinating solvents, such as nitromethane and dichloromethane, the [Pd(dppp)(DPNDI)]4 8+ metallocycle underwent anion exchange in a single-crystal to single-crystal fashion without any structural changes. However, the metallocycle experienced slow dissociation in a polar solvent DMSO, which could be reversed easily by thermal treatment.
Author	Benavides, Paola A Saha, Sourav Gordillo, Monica A
AuthorAffiliation	Department of Chemistry
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Author_xml	– sequence: 1 givenname: Monica A surname: Gordillo fullname: Gordillo, Monica A – sequence: 2 givenname: Paola A orcidid: 0000-0002-1701-5036 surname: Benavides fullname: Benavides, Paola A – sequence: 3 givenname: Sourav orcidid: 0000-0001-6610-4820 surname: Saha fullname: Saha, Sourav email: souravs@clemson.edu
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Cites_doi	10.1021/om500338w 10.1038/nchem.1193 10.1039/c2cc00065b 10.1021/ol302140x 10.1021/ja303173n 10.1039/B518077P 10.1021/cr5005666 10.1021/ja00090a051 10.1021/ol1008558 10.1021/acs.accounts.8b00415 10.1039/c39940002313 10.1021/ja3082473 10.1021/cr200077m 10.1021/acs.cgd.7b01425 10.1039/b812026a 10.1039/B300512G 10.1021/acs.accounts.8b00197 10.1039/C4CS00165F 10.1039/c0dt00766h 10.1039/c3cc43178a 10.1039/C8CS00030A 10.1021/ja00170a042 10.1021/cr3002824 10.1039/c3cc40535d 10.1021/ar9602011 10.1021/ja107382x 10.1039/B614208G 10.1021/ja029648x 10.1021/cm010176f 10.1021/ja004360y 10.1021/ja2055726 10.1080/10610278.2013.872783 10.1126/science.1230444 10.1039/c2cc17459f 10.1039/C2CE06363H 10.1021/ic800334k
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Snippet	A tetrameric metallocycle [Pd(dppp)(DPNDI)]4·8TfO consisting of four dppp-capped Pd(II) corners (dppp = 1,3-bis(diphenylphosphonium)propane) and four...
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Title	Anion/Naphthalenediimide Interactions in a Pd(II)-Based Tetrameric Metallocycle
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