Controlling Structure and Reactivity in Cationic Solid-State Molecular Organometallic Systems Using Anion Templating

The role that the supporting anion has on the stability, structure, and catalytic performance, in solid-state molecular organometallic systems (SMOM) based upon [Rh­(Cy2PCH2CH2PCy2)­(η2η2-NBD)]­[BArX 4], [1-NBD]­[BAr X 4 ], is reported (X = Cl, F, H; NBD = norbornadiene). The tetra-aryl borate anion...

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Bibliographic Details

Published in:	Organometallics Vol. 37; no. 20; pp. 3524 - 3532
Main Authors:	McKay, Alasdair I, Martínez-Martínez, Antonio J, Griffiths, Hannah J, Rees, Nicholas H, Waters, Jordan B, Weller, Andrew S, Krämer, Tobias, Macgregor, Stuart A
Format:	Journal Article
Language:	English
Published:	American Chemical Society 22-10-2018
Online Access:	Get full text
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