Reaction of Triplet Phenylnitrene with Molecular Oxygen

Triplet carbenes react with molecular oxygen with rates that approach diffusion control to carbonyl O-oxides, whereas triplet nitrenes react much slower. For investigating the reaction of phenylnitrene with O2, the nitrene was generated by flash vacuum thermolysis (FVT) of phenylazide and subsequent...

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Bibliographic Details

Published in:	Journal of organic chemistry Vol. 80; no. 24; pp. 11926 - 11931
Main Authors:	Mieres-Pérez, Joel, Mendez-Vega, Enrique, Velappan, Kavitha, Sander, Wolfram
Format:	Journal Article
Language:	English
Published:	United States American Chemical Society 18-12-2015
Online Access:	Get full text
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