Epitaxial Core/Shell Nanocrystals of (Europium-Doped) Zirconia and Hafnia

A careful design of the nanocrystal architecture can strongly enhance the nanocrystal function. So far, this strategy has faced a synthetic bottleneck in the case of refractory oxides. Here we demonstrate the epitaxial growth of hafnia shells onto zirconia cores and pure zirconia shells onto europiu...

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Published in:	Journal of the American Chemical Society Vol. 146; no. 30; pp. 20550 - 20555
Main Authors:	Seno, Carlotta, Reichholf, Nico, Salutari, Francesco, Spadaro, Maria Chiara, Ivanov, Yurii P., Divitini, Giorgio, Gogos, Alexander, Herrmann, Inge K., Arbiol, Jordi, Smet, Philippe F., De Roo, Jonathan
Format:	Journal Article
Language:	English
Published:	United States American Chemical Society 31-07-2024 American Chemical Society (ACS)
Subjects:	Chemistry Communication
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Abstract	A careful design of the nanocrystal architecture can strongly enhance the nanocrystal function. So far, this strategy has faced a synthetic bottleneck in the case of refractory oxides. Here we demonstrate the epitaxial growth of hafnia shells onto zirconia cores and pure zirconia shells onto europium-doped zirconia cores. The core/shell structures are fully crystalline. Upon shelling, the optical properties of the europium dopant are dramatically improved (featuring a more uniform coordination and a longer photoluminescence lifetime), indicating the suppression of nonradiative pathways. These results launch the stable zirconium and hafnium oxide hosts as alternatives for the established NaYF4 systems.
AbstractList	Not provided. A careful design of the nanocrystal architecture can strongly enhance the nanocrystal function. So far, this strategy has faced a synthetic bottleneck in the case of refractory oxides. Here we demonstrate the epitaxial growth of hafnia shells onto zirconia cores and pure zirconia shells onto europium-doped zirconia cores. The core/shell structures are fully crystalline. Upon shelling, the optical properties of the europium dopant are dramatically improved (featuring a more uniform coordination and a longer photoluminescence lifetime), indicating the suppression of nonradiative pathways. These results launch the stable zirconium and hafnium oxide hosts as alternatives for the established NaYF 4 systems. A careful design of the nanocrystal architecture can strongly enhance the nanocrystal function. So far, this strategy has faced a synthetic bottleneck in the case of refractory oxides. Here we demonstrate the epitaxial growth of hafnia shells onto zirconia cores and pure zirconia shells onto europium-doped zirconia cores. The core/shell structures are fully crystalline. Upon shelling, the optical properties of the europium dopant are dramatically improved (featuring a more uniform coordination and a longer photoluminescence lifetime), indicating the suppression of nonradiative pathways. These results launch the stable zirconium and hafnium oxide hosts as alternatives for the established NaYF systems. A careful design of the nanocrystal architecture can strongly enhance the nanocrystal function. So far, this strategy has faced a synthetic bottleneck in the case of refractory oxides. Here we demonstrate the epitaxial growth of hafnia shells onto zirconia cores and pure zirconia shells onto europium-doped zirconia cores. The core/shell structures are fully crystalline. Upon shelling, the optical properties of the europium dopant are dramatically improved (featuring a more uniform coordination and a longer photoluminescence lifetime), indicating the suppression of nonradiative pathways. These results launch the stable zirconium and hafnium oxide hosts as alternatives for the established NaYF4 systems. A careful design of the nanocrystal architecture can strongly enhance the nanocrystal function. So far, this strategy has faced a synthetic bottleneck in the case of refractory oxides. Here we demonstrate the epitaxial growth of hafnia shells onto zirconia cores and pure zirconia shells onto europium-doped zirconia cores. The core/shell structures are fully crystalline. Upon shelling, the optical properties of the europium dopant are dramatically improved (featuring a more uniform coordination and a longer photoluminescence lifetime), indicating the suppression of nonradiative pathways. These results launch the stable zirconium and hafnium oxide hosts as alternatives for the established NaYF4 systems.A careful design of the nanocrystal architecture can strongly enhance the nanocrystal function. So far, this strategy has faced a synthetic bottleneck in the case of refractory oxides. Here we demonstrate the epitaxial growth of hafnia shells onto zirconia cores and pure zirconia shells onto europium-doped zirconia cores. The core/shell structures are fully crystalline. Upon shelling, the optical properties of the europium dopant are dramatically improved (featuring a more uniform coordination and a longer photoluminescence lifetime), indicating the suppression of nonradiative pathways. These results launch the stable zirconium and hafnium oxide hosts as alternatives for the established NaYF4 systems.
Author	Spadaro, Maria Chiara Arbiol, Jordi Divitini, Giorgio Salutari, Francesco Smet, Philippe F. De Roo, Jonathan Reichholf, Nico Ivanov, Yurii P. Herrmann, Inge K. Gogos, Alexander Seno, Carlotta
AuthorAffiliation	Department of Chemistry ICREA Department of Physics and Astronomy “Ettore Majorana” Ghent University Laboratory for Particles-Biology Interactions, Department of Materials Meet Life Electron Spectroscopy and Nanoscopy ETH Zurich Catalan Institute of Nanoscience and Nanotechnology (ICN2), CSIC and BIST Nanoparticle Systems Engineering Laboratory, Institute of Process Engineering, Department of Mechanical and Process Engineering University of Catania and CNR-IMM LumiLab, Department of Solid State Sciences
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Author_xml	– sequence: 1 givenname: Carlotta orcidid: 0000-0002-3565-8086 surname: Seno fullname: Seno, Carlotta organization: Department of Chemistry – sequence: 2 givenname: Nico orcidid: 0000-0003-4064-3011 surname: Reichholf fullname: Reichholf, Nico organization: Department of Chemistry – sequence: 3 givenname: Francesco surname: Salutari fullname: Salutari, Francesco organization: Catalan Institute of Nanoscience and Nanotechnology (ICN2), CSIC and BIST – sequence: 4 givenname: Maria Chiara orcidid: 0000-0002-6540-0377 surname: Spadaro fullname: Spadaro, Maria Chiara organization: University of Catania and CNR-IMM – sequence: 5 givenname: Yurii P. surname: Ivanov fullname: Ivanov, Yurii P. organization: Electron Spectroscopy and Nanoscopy – sequence: 6 givenname: Giorgio orcidid: 0000-0003-2775-610X surname: Divitini fullname: Divitini, Giorgio organization: Electron Spectroscopy and Nanoscopy – sequence: 7 givenname: Alexander surname: Gogos fullname: Gogos, Alexander organization: ETH Zurich – sequence: 8 givenname: Inge K. surname: Herrmann fullname: Herrmann, Inge K. organization: ETH Zurich – sequence: 9 givenname: Jordi orcidid: 0000-0002-0695-1726 surname: Arbiol fullname: Arbiol, Jordi organization: ICREA – sequence: 10 givenname: Philippe F. orcidid: 0000-0003-4789-5799 surname: Smet fullname: Smet, Philippe F. organization: Ghent University – sequence: 11 givenname: Jonathan orcidid: 0000-0002-1264-9312 surname: De Roo fullname: De Roo, Jonathan email: jonathan.deroo@unibas.ch organization: Department of Chemistry
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Snippet	A careful design of the nanocrystal architecture can strongly enhance the nanocrystal function. So far, this strategy has faced a synthetic bottleneck in the... Not provided. A careful design of the nanocrystal architecture can strongly enhance the nanocrystal function. So far, this strategy has faced a synthetic bottleneck in the...
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Title	Epitaxial Core/Shell Nanocrystals of (Europium-Doped) Zirconia and Hafnia
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