Biomarkers in Cretaceous sedimentary rocks from the Codó Formation - Parnaíba Basin: Paleoenvironmental assessment
Earlier geological works showed that Codó Formation - CF (Parnaíba Basin, Brazil) has been deposited in the Aptian, and suffered the influence of various transgressive-regressive marine cycles, thus suggesting various depositional environment possibilities from saline lacustrine deltaic to shallow m...
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| Published in: | Journal of South American earth sciences Vol. 92; pp. 265 - 281 |
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| Main Authors: | , , , , , , , , , , , |
| Format: | Journal Article |
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01-06-2019
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| Abstract | Earlier geological works showed that Codó Formation - CF (Parnaíba Basin, Brazil) has been deposited in the Aptian, and suffered the influence of various transgressive-regressive marine cycles, thus suggesting various depositional environment possibilities from saline lacustrine deltaic to shallow marine during sedimentation. Cretaceous potential source rock samples from the CF were investigated to identify diagnostic biomarkers in order to ascertain paleoenvironmental conditions of deposition and thermal evolution of organic matter. The TOC results showed low organic matter (OM) contents and Rock-Eval analysis implying low thermal evolution of organic matter. GC-MS analysis showed a great diversity of biomarkers within the five studied samples. The main features of organic matter composition were: low content of n-alkanes, Ph » Pr, presence of i-25, i-30 (squalane) and gammacerane thus suggesting saline to hypersaline depositional environment. The biomarkers fingerprint showed a full series of ββ hopanes and Δ13(18) hopenes, αααR and βααR steranes, and Δ5 and Δ8(14) sterenes, pointing out immature OM. Several C30 steranes have been detected, among them 4α(methyl)- and 4β(methyl)-24-ethylcholestane, 24-n-propylcholestane and 24-isopropylcholestane (all identified by co-injection) and dinosteranes, which some of them are indicative of a marine depositional system.
•Cretaceous potential source rock samples from the Codó Formation (Parnaíba Basin, Brazil).•C30 sterane biomarker: 24-n-propylcholestane and 24-isopropylcholestane.•Indicators of maturity and depositional paleoenvironment.•Evidences of anoxia during the deposition of sediments in Parnaíba Basin. |
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| AbstractList | Earlier geological works showed that Codó Formation - CF (Parnaíba Basin, Brazil) has been deposited in the Aptian, and suffered the influence of various transgressive-regressive marine cycles, thus suggesting various depositional environment possibilities from saline lacustrine deltaic to shallow marine during sedimentation. Cretaceous potential source rock samples from the CF were investigated to identify diagnostic biomarkers in order to ascertain paleoenvironmental conditions of deposition and thermal evolution of organic matter. The TOC results showed low organic matter (OM) contents and Rock-Eval analysis implying low thermal evolution of organic matter. GC-MS analysis showed a great diversity of biomarkers within the five studied samples. The main features of organic matter composition were: low content of n-alkanes, Ph » Pr, presence of i-25, i-30 (squalane) and gammacerane thus suggesting saline to hypersaline depositional environment. The biomarkers fingerprint showed a full series of ββ hopanes and Δ13(18) hopenes, αααR and βααR steranes, and Δ5 and Δ8(14) sterenes, pointing out immature OM. Several C30 steranes have been detected, among them 4α(methyl)- and 4β(methyl)-24-ethylcholestane, 24-n-propylcholestane and 24-isopropylcholestane (all identified by co-injection) and dinosteranes, which some of them are indicative of a marine depositional system.
•Cretaceous potential source rock samples from the Codó Formation (Parnaíba Basin, Brazil).•C30 sterane biomarker: 24-n-propylcholestane and 24-isopropylcholestane.•Indicators of maturity and depositional paleoenvironment.•Evidences of anoxia during the deposition of sediments in Parnaíba Basin. |
| Author | Cioccari, Giovani M. Capilla, Ramsés Júnior, Gustavo R.Sousa Imamura, Paulo M. de A. M. Reis, Francisco Rodrigues, Rene Lopes, José A.D. de Lima, Sidney G. da S. Sousa, Edymilaís de Sousa, Alek A.C. de Souza, Igor V.A.F. Silva, Andrenilton F. |
| Author_xml | – sequence: 1 givenname: Edymilaís surname: da S. Sousa fullname: da S. Sousa, Edymilaís organization: Laboratory of Organic Geochemistry, Center of Natural Sciences, Federal University of Piaui, Campus Ministro Petrônio Portela, 64049-550, Teresina, PI, Brazil – sequence: 2 givenname: Gustavo R.Sousa surname: Júnior fullname: Júnior, Gustavo R.Sousa organization: Chemistry Institute, University of Campinas, Box 6154, 13083-970, Campinas, SP, Brazil – sequence: 3 givenname: Andrenilton F. surname: Silva fullname: Silva, Andrenilton F. organization: Laboratory of Organic Geochemistry, Center of Natural Sciences, Federal University of Piaui, Campus Ministro Petrônio Portela, 64049-550, Teresina, PI, Brazil – sequence: 4 givenname: Francisco surname: de A. M. Reis fullname: de A. M. Reis, Francisco organization: Chemistry Institute, University of Campinas, Box 6154, 13083-970, Campinas, SP, Brazil – sequence: 5 givenname: Alek A.C. surname: de Sousa fullname: de Sousa, Alek A.C. organization: Laboratory of Organic Geochemistry, Center of Natural Sciences, Federal University of Piaui, Campus Ministro Petrônio Portela, 64049-550, Teresina, PI, Brazil – sequence: 6 givenname: Giovani M. surname: Cioccari fullname: Cioccari, Giovani M. organization: Federal University of Pelotas, Engineering Centre, 96010-640, Pelotas, RS, Brazil – sequence: 7 givenname: Ramsés surname: Capilla fullname: Capilla, Ramsés organization: Petrobras/CENPES/PDEP/GEOQ, Av. Horácio Macedo 950, Universitária-Ilha do Fundã City, 21941-915, Rio de Janeiro, RJ, Brazil – sequence: 8 givenname: Igor V.A.F. surname: de Souza fullname: de Souza, Igor V.A.F. organization: Petrobras/CENPES/PDEP/GEOQ, Av. Horácio Macedo 950, Universitária-Ilha do Fundã City, 21941-915, Rio de Janeiro, RJ, Brazil – sequence: 9 givenname: Paulo M. surname: Imamura fullname: Imamura, Paulo M. organization: Chemistry Institute, University of Campinas, Box 6154, 13083-970, Campinas, SP, Brazil – sequence: 10 givenname: Rene surname: Rodrigues fullname: Rodrigues, Rene organization: Rio de Janeiro State University, Faculty of Geology, Department of Stratigraphy and Paleontology, 20559-900, Rio de Janeiro, RJ, Brazil – sequence: 11 givenname: José A.D. surname: Lopes fullname: Lopes, José A.D. organization: Laboratory of Organic Geochemistry, Center of Natural Sciences, Federal University of Piaui, Campus Ministro Petrônio Portela, 64049-550, Teresina, PI, Brazil – sequence: 12 givenname: Sidney G. surname: de Lima fullname: de Lima, Sidney G. email: sidney@ufpi.edu.br organization: Laboratory of Organic Geochemistry, Center of Natural Sciences, Federal University of Piaui, Campus Ministro Petrônio Portela, 64049-550, Teresina, PI, Brazil |
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