Synthesis, Structures, and Stereodynamic Behavior of Novel Pentacoordinate Fluorosilanes: Fluorosilyl Derivatives of Proline

The (O→Si)-chelate N′-(dimethylfluorosilylmethyl))-N′-methyl-N-(organosulfonyl)prolinamides RSO2-Pro-N(Me)CH2SiMe2F (2a–f, R = Me (a), Ph (b), 4-MeC6H4 (c), 4-ClC6H4 (d), 4-BrC6H4 (e), 4-NO2C6H4 (f)) were synthesized from the corresponding disiloxanes 1a–f using Et2O·BF3. According to the NMR and IR...

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Bibliographic Details

Published in:	Organometallics Vol. 31; no. 14; pp. 4988 - 4997
Main Authors:	Nikolin, Alexei A., Kramarova, Evgeniya P., Shipov, Aleksander G., Baukov, Yuri I., Negrebetsky, Vadim V., Korlyukov, Alexander A., Arkhipov, Dmitry E., Bowden, Allen, Bylikin, Sergey Yu, Bassindale, Alan R., Taylor, Peter G.
Format:	Journal Article
Language:	English
Published:	American Chemical Society 23-07-2012
Online Access:	Get full text
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