Structure and Reactivity of Chromium(VI) Alkylidenes

Bis­(arylimido)­Cr­(VI) dialkyls lacking β-hydrogen decompose by α-hydrogen abstraction and, upon trapping with triphenylphosphine, yield isolable alkylidene complexes. Two such complexes, namely (ArN)2CrCHR­(PPh3) (R = tBu, SiMe3), have been structurally characterized. The coordinatively unsaturat...

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Bibliographic Details

Published in:	Journal of the American Chemical Society Vol. 140; no. 23; pp. 7088 - 7091
Main Authors:	Wu, Pengcheng, Yap, Glenn P. A, Theopold, Klaus H
Format:	Journal Article
Language:	English
Published:	United States American Chemical Society 13-06-2018
Online Access:	Get full text
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