Selective N Functionalization of Methane and Ethane to Aminated Derivatives by Main-Group-Directed C–H Activation

To our knowledge, there is no precedent for the direct conversion of light alkanes to aminated products by CH activation. Previous molecular systems reported for alkane amination operate by radical or nitrene-type reactions which generally result in unintended overfunctionalization. Here we disclose...

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Bibliographic Details

Published in:	Organometallics Vol. 38; no. 11; pp. 2319 - 2322
Main Authors:	Gunsalus, Niles Jensen, Park, Sae Hume, Hashiguchi, Brian G, Koppaka, Anjaneyulu, Smith, Stacey J, Ess, Daniel H, Periana, Roy A
Format:	Journal Article
Language:	English
Published:	United States American Chemical Society 10-06-2019
Subjects:	Chemistry
Online Access:	Get full text
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