Impact of Cr Doping on the Structural, Optical, and Magnetic Properties of Sol–Gel-Synthesized Bi0.80Ba0.10Pr0.10FeO3 Nanopowders

• Published in: ACS omega Vol. 9; no. 25; pp. 27549 - 27558
• Main Authors: Sharma, Subhash, Rojas-George, Gabriel, Kumar, Manish, Kumar, Pawan, Kumar, Rajesh, Kumar, Santosh, Siqueiros, Jesús M., Herrera, Oscar Raymond
• Format: Journal Article
• Language: English
• Published: American Chemical Society 25-06-2024
• ISSN: 2470-1343; 2470-1343
• DOI: 10.1021/acsomega.4c03032

The sol–gel route was used to synthesize a series of compounds of the system Bi0.8Ba0.10Pr0.10Fe1–x Cr x O3 within the 0 ≤ x ≤ 0.15 compositional range. To explore the impact of Cr3+ ion substitution on the structural, dielectric, optical, and magnetic properties, we introduced varying concentrations of Cr3+ while maintaining a fixed 10% atomic concentration of each Ba2+ and Pr2+ in BiFeO3. X-ray diffraction analysis revealed a structural phase transition from rhombohedral (R3c) for an undoped (i.e., without Cr) sample to two coexisting phases, i.e., a mix of rhombohedral and orthorhombic (Pbnm) phases for the Cr-doped samples. Cr3+ doping significantly changes the band gap energy from 1.84 eV (x = 0.0) to 1.93 eV (x = 0.15), which makes this material suitable for photovoltaic applications. Furthermore, each sample exhibited ferromagnetic behavior due to the disruption of the spiral spin structures and adjustments in superexchange interactions, attributed to modifications in the Fe–O and Fe–O–Fe bond lengths. A reduction in magnetization is observed at higher Cr concentrations that can be ascribed to the dilution of magnetic moments due to the increase of the orthorhombic phase percentage and the introduction of nonmagnetic Cr3+ ions. Our results show that Cr doping in the Bi0.8Ba0.10Pr0.10FeO3 system induces enhanced multiferroic properties at room temperature.