First Example of a Reversible Single-Crystal-to-Single-Crystal Polymerization–Depolymerization Accompanied by a Magnetic Anomaly for a Transition-Metal Complex with an Organic Radical

The reaction of copper(II) hexafluoroacetylacetonate [Cu(hfac)2] with the stable nitronyl nitroxide 2-(1-ethyl-3-methyl-1H-pyrazol-4-yl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazole-3-oxide-1-oxyl (La) resulted in a paired heterospin complex [[Cu(hfac)2]3(μ-O,N-La)2][Cu(hfac)2(O-La)2]. The crystals...

Full description

Bibliographic Details

Published in:	Inorganic chemistry Vol. 51; no. 22; pp. 12188 - 12194
Main Authors:	Ovcharenko, Victor I, Fokin, Sergey V, Kostina, Elvina T, Romanenko, Galina V, Bogomyakov, Artem S, Tretyakov, Eugene V
Format:	Journal Article
Language:	English
Published:	United States American Chemical Society 19-11-2012
Online Access:	Get full text
Tags:	Add Tag No Tags, Be the first to tag this record!