Oxygen Binding to [Pd(L)(L′)] (L= NHC, L′ = NHC or PR3, NHC = N-Heterocyclic Carbene). Synthesis and Structure of a Paramagnetic trans-[Pd(NHC)2(η1-O2)2] Complex

The reactivity of a number of two-coordinate [Pd(L)(L′)] (L = N-heterocyclic carbene (NHC) and L′ = NHC or PR3) complexes with O2 has been examined. Stopped-flow kinetic studies show that O2 binding to [Pd(IPr)(P(p-tolyl)3)] to form cis-[Pd(IPr)(P(p-tolyl)3)(η2-O2)] occurs in a rapid, second-order p...

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Bibliographic Details

Published in:	Journal of the American Chemical Society Vol. 133; no. 5; pp. 1290 - 1293
Main Authors:	Cai, Xiaochen, Majumdar, Subhojit, Fortman, George C, Cazin, Catherine S. J, Slawin, Alexandra M. Z, Lhermitte, Charles, Prabhakar, Rajeev, Germain, Meaghan E, Palluccio, Taryn, Nolan, Steven P, Rybak-Akimova, Elena V, Temprado, Manuel, Captain, Burjor, Hoff, Carl D
Format:	Journal Article
Language:	English
Published:	United States American Chemical Society 09-02-2011
Online Access:	Get full text
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