Deposition Dynamics of Hydrogenated Silicon Clusters on a Crystalline Silicon Substrate under Typical Plasma Conditions

We have studied the deposition dynamics of hydrogenated silicon clusters on a silicon substrate for various cluster sizes and impact energies. The results show that the interaction processes of silicon nanocrystals with a crystalline silicon substrate strongly depend on the impact energy ranging fro...

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Bibliographic Details
Published in:The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Vol. 114; no. 9; pp. 3297 - 3305
Main Authors: Ning, Ning, Vach, Holger
Format: Journal Article
Language:English
Published: United States American Chemical Society 11-03-2010
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Summary:We have studied the deposition dynamics of hydrogenated silicon clusters on a silicon substrate for various cluster sizes and impact energies. The results show that the interaction processes of silicon nanocrystals with a crystalline silicon substrate strongly depend on the impact energy ranging from elastic scattering over soft-landing to cluster destruction with penetration of some cluster atoms into the substrate. Under certain conditions, epitaxial-like recrystallization of clusters has been observed after the initial cluster structure was completely lost upon surface impact. The reaction mechanisms as a function of impact energy are in good agreement with recent experimental results.
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ISSN:1089-5639
1520-5215
DOI:10.1021/jp909446c