Controlling Bandgap of Rippled Hexagonal Boron Nitride Membranes via Plasma Treatment

Few-layer rippled hexagonal boron nitride (h-BN) membranes were processed with hydrogen plasma, which exhibit distinct and pronounced changes in its electronic properties after the plasma treatment. The bandgaps of the h-BN membrane reduced from ∼5.6 eV at 0 s to ∼4.25 eV at 250s, which is a signatu...

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Published in:ACS applied materials & interfaces Vol. 4; no. 1; pp. 30 - 33
Main Authors: Zhang, H. X, Feng, P. X
Format: Journal Article
Language:English
Published: United States American Chemical Society 25-01-2012
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Abstract Few-layer rippled hexagonal boron nitride (h-BN) membranes were processed with hydrogen plasma, which exhibit distinct and pronounced changes in its electronic properties after the plasma treatment. The bandgaps of the h-BN membrane reduced from ∼5.6 eV at 0 s to ∼4.25 eV at 250s, which is a signature of transition from the insulating to the semiconductive regime. It typically required 250 s of plasma treatment to reach the saturation. It illustrates that two-dimensional material with engineered electronic properties can be created by attaching other atoms or molecules.
AbstractList Few-layer rippled hexagonal boron nitride (h-BN) membranes were processed with hydrogen plasma, which exhibit distinct and pronounced changes in its electronic properties after the plasma treatment. The bandgaps of the h-BN membrane reduced from ~5.6 eV at 0 s to ~4.25 eV at 250 s, which is a signature of transition from the insulating to the semiconductive regime. It typically required 250 s of plasma treatment to reach the saturation. It illustrates that two-dimensional material with engineered electronic properties can be created by attaching other atoms or molecules.
Few-layer rippled hexagonal boron nitride (h-BN) membranes were processed with hydrogen plasma, which exhibit distinct and pronounced changes in its electronic properties after the plasma treatment. The bandgaps of the h-BN membrane reduced from ∼5.6 eV at 0 s to ∼4.25 eV at 250s, which is a signature of transition from the insulating to the semiconductive regime. It typically required 250 s of plasma treatment to reach the saturation. It illustrates that two-dimensional material with engineered electronic properties can be created by attaching other atoms or molecules.
Author Zhang, H. X
Feng, P. X
AuthorAffiliation University of Puerto Rico
National Laboratory
AuthorAffiliation_xml – name: University of Puerto Rico
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  givenname: H. X
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  fullname: Zhang, H. X
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  givenname: P. X
  surname: Feng
  fullname: Feng, P. X
  email: p.feng@upr.edu
BackLink https://www.ncbi.nlm.nih.gov/pubmed/22201217$$D View this record in MEDLINE/PubMed
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Issue 1
Keywords ripples
h-BN membrane
bandgap
plasma
hydrogenation
TEM
Language English
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Snippet Few-layer rippled hexagonal boron nitride (h-BN) membranes were processed with hydrogen plasma, which exhibit distinct and pronounced changes in its electronic...
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Title Controlling Bandgap of Rippled Hexagonal Boron Nitride Membranes via Plasma Treatment
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