Self-Assembling of n-Type Semiconductor Tri(phenanthrolino)hexaazatriphenylenes with a Large Aromatic Core

Self-Assembling of n-Type Semiconductor Tri(phenanthrolino)hexaazatriphenylenes with a Large Aromatic Core

Large disk-shaped aromatic tri(phenanthrolino)hexaazatriphenylenes 5a, 5b, and 5c with six butyl, dodecyl, and 4-octylphenyl groups, respectively, were self-assembled both in solution and film state to form one-dimensional aggregates. Their n-type semiconducting nature was indicated from CV measurem...

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Bibliographic Details
Published in:Organic letters Vol. 8; no. 4; pp. 585 - 588
Main Authors: Ishi-i, Tsutomu, Yaguma, Kentaro, Kuwahara, Rempei, Taguri, Yoshiki, Mataka, Shuntaro
Format: Journal Article
Language:English
Published: United States American Chemical Society 16-02-2006
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Summary:Large disk-shaped aromatic tri(phenanthrolino)hexaazatriphenylenes 5a, 5b, and 5c with six butyl, dodecyl, and 4-octylphenyl groups, respectively, were self-assembled both in solution and film state to form one-dimensional aggregates. Their n-type semiconducting nature was indicated from CV measurement, in which the first reduction potentials were evaluated at around −1.7 V (vs Fc/Fc+) in dichloromethane.
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ISSN:1523-7060
1523-7052
DOI:10.1021/ol052779t