Highly Diastereoselective Diels−Alder Reactions of Baylis−Hillman Adducts

Highly Diastereoselective Diels−Alder Reactions of Baylis−Hillman Adducts

Baylis−Hillman adducts were found to be excellent dienophiles in Diels−Alder reactions, providing essentially complete diastereocontrol (although mixtures of endo/exo isomers) with all dienes.

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Bibliographic Details
Published in:Organic letters Vol. 7; no. 13; pp. 2555 - 2557
Main Authors: Aggarwal, Varinder K, Patin, Amaury, Tisserand, Steve
Format: Journal Article
Language:English
Published: United States American Chemical Society 23-06-2005
Online Access:Get full text
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Description
Summary:Baylis−Hillman adducts were found to be excellent dienophiles in Diels−Alder reactions, providing essentially complete diastereocontrol (although mixtures of endo/exo isomers) with all dienes.
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ISSN:1523-7060
1523-7052
DOI:10.1021/ol050584f