Determining the Thermal Properties of Military Jet Fuel JP‑5 and Surrogate Mixtures Using Differential Scanning Calorimetry/Thermogravimetric Analysis and Differential Scanning Calorimetry Methods

Determining the Thermal Properties of Military Jet Fuel JP‑5 and Surrogate Mixtures Using Differential Scanning Calorimetry/Thermogravimetric Analysis and Differential Scanning Calorimetry Methods

Heat capacity and heat of vaporization (HoV) are thermal properties that affect the combustion of fuels in engines. This study highlights new calorimetric methods to measure the thermal properties of JP-5 and surrogate fuel systems. First, the heat capacities of military jet fuel (JP-5) and surrogat...

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Published in:Energy & fuels Vol. 34; no. 4; pp. 4046 - 4054
Main Authors: Luning Prak, Dianne J, Foley, Matthew P, Dorn, Ladavish, Trulove, Paul C, Cowart, Jim S, Durkin, David P
Format: Journal Article
Language:English
Published: American Chemical Society 16-04-2020
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Abstract Heat capacity and heat of vaporization (HoV) are thermal properties that affect the combustion of fuels in engines. This study highlights new calorimetric methods to measure the thermal properties of JP-5 and surrogate fuel systems. First, the heat capacities of military jet fuel (JP-5) and surrogate fuel mixtures were measured using a stand-alone differential scanning calorimeter. The surrogates consisted of two-component and four-component mixtures, which have been reported in past studies. Six quaternary and four binary mixtures had heat capacities matching those of JP-5 at 20 °C, 1.91 ± 0.03 J·g–1 °C, within a 90% confidence interval. The heats (energy) needed to evaporate JP-5 and each surrogate mixture were determined using a differential scanning calorimetry–thermogravimetric analysis system. Isothermal measurements were used to measure pure components. A temperature ramping protocol was designed for JP-5 and surrogate mixtures. The HoV of JP-5 was determined to be 239 ± 8 J·g–1, which falls within the range of literature values based on predictive correlations. The HoVs for six of the surrogate mixtures matched those of JP-5 within their 90% confidence intervals.
AbstractList Heat capacity and heat of vaporization (HoV) are thermal properties that affect the combustion of fuels in engines. This study highlights new calorimetric methods to measure the thermal properties of JP-5 and surrogate fuel systems. First, the heat capacities of military jet fuel (JP-5) and surrogate fuel mixtures were measured using a stand-alone differential scanning calorimeter. The surrogates consisted of two-component and four-component mixtures, which have been reported in past studies. Six quaternary and four binary mixtures had heat capacities matching those of JP-5 at 20 °C, 1.91 ± 0.03 J·g–1 °C, within a 90% confidence interval. The heats (energy) needed to evaporate JP-5 and each surrogate mixture were determined using a differential scanning calorimetry–thermogravimetric analysis system. Isothermal measurements were used to measure pure components. A temperature ramping protocol was designed for JP-5 and surrogate mixtures. The HoV of JP-5 was determined to be 239 ± 8 J·g–1, which falls within the range of literature values based on predictive correlations. The HoVs for six of the surrogate mixtures matched those of JP-5 within their 90% confidence intervals.
Author Durkin, David P
Foley, Matthew P
Cowart, Jim S
Dorn, Ladavish
Luning Prak, Dianne J
Trulove, Paul C
AuthorAffiliation Department of Chemistry
Department of Mechanical Engineering
U.S. Naval Academy Preparatory School
U.S. Naval Academy
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CitedBy_id crossref_primary_10_1016_j_fuel_2023_129291
crossref_primary_10_1016_j_fuel_2024_132070
Cites_doi 10.1021/je60025a047
10.1021/ef050116m
10.1007/s40430-013-0094-y
10.1016/s0040-6031(97)00364-x
10.1201/9781420086058
10.4271/2016-01-0836
10.1021/ef402491p
10.1021/ie050113x
10.2514/3.23168
10.1021/je030236t
10.1016/s0021-9673(00)86297-4
10.1021/acs.jced.8b01233
10.18434/T4D303
10.1016/j.ces.2005.03.005
10.1021/je1004824
10.1520/MNL50_1ST-EB
10.1021/jo00334a040
10.1063/1.555883
10.3390/pr5040080
10.1021/ef1015796
10.1080/00986440108912849
10.1039/f29747001479
10.1016/j.fuel.2019.03.096
10.6028/jres.023.008
10.1016/j.fuel.2006.08.008
10.2514/6.2017-0146
10.4271/2008-01-0317
10.1016/0300-9467(79)85008-x
10.1016/S0082-0784(88)80292-3
10.1063/1.3472283
10.4271/2015-01-0763
10.1016/j.jct.2017.03.034
10.1021/acs.iecr.6b04772
10.4271/2009-01-0324
10.1016/j.fuel.2016.03.085
10.1002/cite.330260206
10.1021/ie300375k
10.1021/acs.energyfuels.8b03369
10.1021/j100890a048
10.1021/j100486a009
10.1080/00986448708960487
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References ref9/cit9
ref6/cit6
ref36/cit36
ref3/cit3
ref27/cit27
Viton C. (ref16/cit16) 1996; 2
ref11/cit11
Callahan J. E. (ref18/cit18) 1988
ref29/cit29
Sauerbrunn S. (ref17/cit17) 2009; 18
(ref33/cit33) 2012
Nelson W. L. (ref45/cit45) 1958
ref32/cit32
ref23/cit23
ref39/cit39
ref14/cit14
ref8/cit8
ref5/cit5
ref31/cit31
ref2/cit2
Reid R. C. (ref25/cit25) 1987
ref43/cit43
ref34/cit34
ref37/cit37
ref28/cit28
ref40/cit40
ref20/cit20
ref48/cit48
ref10/cit10
ref26/cit26
Lefebvre A. H. (ref44/cit44) 2010
ref35/cit35
ref19/cit19
ref21/cit21
ref12/cit12
ref15/cit15
ref42/cit42
ref46/cit46
ref41/cit41
ref22/cit22
ref13/cit13
ref4/cit4
ref30/cit30
ref47/cit47
ref1/cit1
ref24/cit24
ref38/cit38
ref7/cit7
References_xml – ident: ref21/cit21
  doi: 10.1021/je60025a047
– ident: ref14/cit14
– volume-title: Standard Test Method for Determining Specific Heat Capacity by Differential Scanning Calorimetry
  year: 2012
  ident: ref33/cit33
– ident: ref43/cit43
  doi: 10.1021/ef050116m
– ident: ref47/cit47
  doi: 10.1007/s40430-013-0094-y
– ident: ref39/cit39
  doi: 10.1016/s0040-6031(97)00364-x
– volume-title: Gas Turbine Combustion: Alternative Fuels and Emissions
  year: 2010
  ident: ref44/cit44
  doi: 10.1201/9781420086058
  contributor:
    fullname: Lefebvre A. H.
– ident: ref4/cit4
  doi: 10.4271/2016-01-0836
– ident: ref10/cit10
  doi: 10.1021/ef402491p
– ident: ref26/cit26
  doi: 10.1021/ie050113x
– ident: ref32/cit32
  doi: 10.2514/3.23168
– ident: ref13/cit13
  doi: 10.1021/je030236t
– ident: ref12/cit12
  doi: 10.1016/s0021-9673(00)86297-4
– ident: ref30/cit30
  doi: 10.1021/acs.jced.8b01233
– volume-title: Properties of Gases and Liquids
  year: 1987
  ident: ref25/cit25
  contributor:
    fullname: Reid R. C.
– ident: ref11/cit11
  doi: 10.18434/T4D303
– ident: ref29/cit29
  doi: 10.1016/j.ces.2005.03.005
– ident: ref19/cit19
  doi: 10.1021/je1004824
– ident: ref28/cit28
  doi: 10.1520/MNL50_1ST-EB
– ident: ref7/cit7
  doi: 10.1021/jo00334a040
– ident: ref37/cit37
  doi: 10.1063/1.555883
– volume-title: Development of Standard Measurement Techniques and Standard Reference Materials for Heat Capacity and Heat of Vaporization of Jet Fuels
  year: 1988
  ident: ref18/cit18
  contributor:
    fullname: Callahan J. E.
– ident: ref46/cit46
  doi: 10.3390/pr5040080
– ident: ref48/cit48
  doi: 10.1021/ef1015796
– ident: ref23/cit23
  doi: 10.1080/00986440108912849
– ident: ref41/cit41
  doi: 10.1039/f29747001479
– ident: ref31/cit31
  doi: 10.1016/j.fuel.2019.03.096
– ident: ref15/cit15
  doi: 10.6028/jres.023.008
– ident: ref8/cit8
  doi: 10.1016/j.fuel.2006.08.008
– ident: ref42/cit42
  doi: 10.2514/6.2017-0146
– ident: ref9/cit9
  doi: 10.4271/2008-01-0317
– ident: ref22/cit22
  doi: 10.1016/0300-9467(79)85008-x
– ident: ref2/cit2
  doi: 10.1016/S0082-0784(88)80292-3
– ident: ref35/cit35
  doi: 10.1063/1.3472283
– ident: ref6/cit6
  doi: 10.4271/2015-01-0763
– ident: ref36/cit36
  doi: 10.1016/j.jct.2017.03.034
– ident: ref27/cit27
  doi: 10.1021/acs.iecr.6b04772
– ident: ref3/cit3
  doi: 10.4271/2009-01-0324
– ident: ref1/cit1
  doi: 10.1016/j.fuel.2016.03.085
– ident: ref20/cit20
  doi: 10.1002/cite.330260206
– volume-title: Petroleum Refinery Engineering
  year: 1958
  ident: ref45/cit45
  contributor:
    fullname: Nelson W. L.
– ident: ref34/cit34
  doi: 10.1021/ie300375k
– ident: ref5/cit5
  doi: 10.1021/acs.energyfuels.8b03369
– ident: ref38/cit38
  doi: 10.1021/j100890a048
– ident: ref40/cit40
  doi: 10.1021/j100486a009
– volume: 18
  start-page: 18
  year: 2009
  ident: ref17/cit17
  publication-title: Am. Lab.
  contributor:
    fullname: Sauerbrunn S.
– ident: ref24/cit24
  doi: 10.1080/00986448708960487
– volume: 2
  start-page: 103
  year: 1996
  ident: ref16/cit16
  publication-title: ELDATA: Int. Electron. J. Phys.-Chem. Data
  contributor:
    fullname: Viton C.
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Snippet Heat capacity and heat of vaporization (HoV) are thermal properties that affect the combustion of fuels in engines. This study highlights new calorimetric...
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Title Determining the Thermal Properties of Military Jet Fuel JP‑5 and Surrogate Mixtures Using Differential Scanning Calorimetry/Thermogravimetric Analysis and Differential Scanning Calorimetry Methods
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