Effects of Intra- and Intercenter Interactions in Spin Crossover:  Application of the Density Matrix Method to the Nonequilibrium Low-Spin↔High-Spin Transitions Induced by Light

Effects of Intra- and Intercenter Interactions in Spin Crossover:  Application of the Density Matrix Method to the Nonequilibrium Low-Spin↔High-Spin Transitions Induced by Light

A microscopic model of nonequilibrium light-induced phase transitions in spin crossover systems based on the solution of the equations for the density operator is developed. The conditions of light-induced and thermally induced bistability are revealed. The results are compared with those obtained i...

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Bibliographic Details
Published in:Journal of physical chemistry. C Vol. 111; no. 28; pp. 10644 - 10651
Main Authors: Klokishner, S, Linares, J
Format: Journal Article
Language:English
Published: American Chemical Society 19-07-2007
Online Access:Get full text
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Summary:A microscopic model of nonequilibrium light-induced phase transitions in spin crossover systems based on the solution of the equations for the density operator is developed. The conditions of light-induced and thermally induced bistability are revealed. The results are compared with those obtained in the framework of the Glauber's approach. The qualitative explanation of experimental data on a series of spin crossover systems is given.
Bibliography:istex:106A3B7C18CA385977A81FB2D6D4CAEFCEA6286D
ark:/67375/TPS-ZXQPMC1Z-V
ISSN:1932-7447
1932-7455
DOI:10.1021/jp070126j