X-ray and NOE Studies on Trinuclear Iridium Hydride Phosphino Oxazoline (PHOX) Complexes
Two trinuclear iridium hydride clusters of the type [Ir3(μ3-H)(H)6(PHOX)3]X1X2 (X1 = PF6, X2 = OTf; X1 = X2 = PF6; X1 = X2 = OTf; PHOX = (S)-4-tert-butyl-2-[2-(di-o-tolylphosphinyl)phenyl]-4,5-dihydrooxazole, (S)-2-[2-(diphenylphosphinyl)phenyl]-4-isopropyl-4,5-dihydrooxazole) have been prepared and...
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| Published in: | Organometallics Vol. 22; no. 5; pp. 1000 - 1009 |
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| Main Authors: | , , , , |
| Format: | Journal Article |
| Language: | English |
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American Chemical Society
03-03-2003
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| Abstract | Two trinuclear iridium hydride clusters of the type [Ir3(μ3-H)(H)6(PHOX)3]X1X2 (X1 = PF6, X2 = OTf; X1 = X2 = PF6; X1 = X2 = OTf; PHOX = (S)-4-tert-butyl-2-[2-(di-o-tolylphosphinyl)phenyl]-4,5-dihydrooxazole, (S)-2-[2-(diphenylphosphinyl)phenyl]-4-isopropyl-4,5-dihydrooxazole) have been prepared and characterized by X-ray diffraction and multidimensional NMR. They contain a single bridging hydride in pseudo-trans position to the P-donors. The complexed PHOX ligands reveal a chiral pocket involving one pseudoequatorial P-aryl substituent and one pseudoaxial (proximate to the oxazoline substituent) P-aryl group. These trinuclear complexes are shown to be inactive as hydrogenation catalysts. |
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| AbstractList | Two trinuclear iridium hydride clusters of the type [Ir3(μ3-H)(H)6(PHOX)3]X1X2 (X1 = PF6, X2 = OTf; X1 = X2 = PF6; X1 = X2 = OTf; PHOX = (S)-4-tert-butyl-2-[2-(di-o-tolylphosphinyl)phenyl]-4,5-dihydrooxazole, (S)-2-[2-(diphenylphosphinyl)phenyl]-4-isopropyl-4,5-dihydrooxazole) have been prepared and characterized by X-ray diffraction and multidimensional NMR. They contain a single bridging hydride in pseudo-trans position to the P-donors. The complexed PHOX ligands reveal a chiral pocket involving one pseudoequatorial P-aryl substituent and one pseudoaxial (proximate to the oxazoline substituent) P-aryl group. These trinuclear complexes are shown to be inactive as hydrogenation catalysts. |
| Author | Pfaltz, Andreas Martínez-Viviente, Eloísa Albinati, Alberto Smidt, Sebastian P Pregosin, Paul S |
| Author_xml | – sequence: 1 givenname: Sebastian P surname: Smidt fullname: Smidt, Sebastian P – sequence: 2 givenname: Andreas surname: Pfaltz fullname: Pfaltz, Andreas – sequence: 3 givenname: Eloísa surname: Martínez-Viviente fullname: Martínez-Viviente, Eloísa – sequence: 4 givenname: Paul S surname: Pregosin fullname: Pregosin, Paul S – sequence: 5 givenname: Alberto surname: Albinati fullname: Albinati, Alberto |
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| Snippet | Two trinuclear iridium hydride clusters of the type [Ir3(μ3-H)(H)6(PHOX)3]X1X2 (X1 = PF6, X2 = OTf; X1 = X2 = PF6; X1 = X2 = OTf; PHOX =... |
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| Title | X-ray and NOE Studies on Trinuclear Iridium Hydride Phosphino Oxazoline (PHOX) Complexes |
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