Asymmetric Construction of a Ferrocenyl Phosphapalladacycle from Achiral Enones and a Demonstration of Its Catalytic Potential

Asymmetric Construction of a Ferrocenyl Phosphapalladacycle from Achiral Enones and a Demonstration of Its Catalytic Potential

A new approach toward ferrocenyl phosphapalladacycle construction from achiral enones via asymmetric hydrophosphination and subsequent diastereoselective C–H activation is described. Its catalytic efficacy toward C–C bond formation is subsequently illustrated.

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Bibliographic Details
Published in:Organometallics Vol. 33; no. 19; pp. 5074 - 5076
Main Authors: Gan, Kennard, Sadeer, Abdul, Xu, Chang, Li, Yongxin, Pullarkat, Sumod A
Format: Journal Article
Language:English
Published: American Chemical Society 13-10-2014
Online Access:Get full text
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Description
Summary:A new approach toward ferrocenyl phosphapalladacycle construction from achiral enones via asymmetric hydrophosphination and subsequent diastereoselective C–H activation is described. Its catalytic efficacy toward C–C bond formation is subsequently illustrated.
ISSN:0276-7333
1520-6041
DOI:10.1021/om5007215