Photocatalytic Method for the Simultaneous Synthesis and Immobilization of Ag Nanoparticles onto Solid Substrates

A photocatalytic method based on layer-by-layer photocatalyst films made of titanium dioxide nanoparticles and graphene oxide, TiO2NPs/GO, is proposed for performing the synthesis and immobilization of spherical AgNPs simultaneously using diluted AgNO3 solutions and UV irradiation (254 nm). The nove...

Full description

Saved in:

Bibliographic Details
Published in:	Journal of physical chemistry. C Vol. 122; no. 42; pp. 24110 - 24119
Main Authors:	Costa, Ítalo A, Maciel, Ayessa P, Sales, Maria José A, Rivera, Luis Miguel R, Soler, Maria A. G, Pereira-da-Silva, Marcelo A, Moreira, Sanclayton G. C, Paterno, Leonardo G
Format:	Journal Article
Language:	English
Published:	American Chemical Society 25-10-2018
Online Access:	Get full text
Tags:	Add Tag No Tags, Be the first to tag this record!

Abstract	A photocatalytic method based on layer-by-layer photocatalyst films made of titanium dioxide nanoparticles and graphene oxide, TiO2NPs/GO, is proposed for performing the synthesis and immobilization of spherical AgNPs simultaneously using diluted AgNO3 solutions and UV irradiation (254 nm). The novelty provided by this method is that the amount and aggregation extent of AgNPs can be controlled by the number of TiO2NP/GO bilayers and the composition of the outermost layer in the photocatalyst film. When the outermost layer is made of GO, more AgNPs are deposited because GO serves as an anchoring harbor for Ag+ ions and a venue to the transportation of photoexcited electrons for subsequent photo reduction to Ag0. The photodeposition follows a first-order kinetics, whereas in the equilibrium it can be fitted by the Langmuir isotherm model for which surface coverage as high as 60% is attained after 70 min of UV irradiation. The TiO2NP/GO/AgNP substrates show surface-enhanced resonant Raman scattering (SERRS) activity for nickel(II) phthalocyanine-tetrasulfonic acid tetrasodium salt (NiTsPc). The SERRS activity is ascribed to a combination of local electromagnetic field enhancement because of the plasmon resonance of AgNPs and proper excitation of samples in resonance with the Q-band of NiTsPc.
AbstractList	A photocatalytic method based on layer-by-layer photocatalyst films made of titanium dioxide nanoparticles and graphene oxide, TiO2NPs/GO, is proposed for performing the synthesis and immobilization of spherical AgNPs simultaneously using diluted AgNO3 solutions and UV irradiation (254 nm). The novelty provided by this method is that the amount and aggregation extent of AgNPs can be controlled by the number of TiO2NP/GO bilayers and the composition of the outermost layer in the photocatalyst film. When the outermost layer is made of GO, more AgNPs are deposited because GO serves as an anchoring harbor for Ag+ ions and a venue to the transportation of photoexcited electrons for subsequent photo reduction to Ag0. The photodeposition follows a first-order kinetics, whereas in the equilibrium it can be fitted by the Langmuir isotherm model for which surface coverage as high as 60% is attained after 70 min of UV irradiation. The TiO2NP/GO/AgNP substrates show surface-enhanced resonant Raman scattering (SERRS) activity for nickel(II) phthalocyanine-tetrasulfonic acid tetrasodium salt (NiTsPc). The SERRS activity is ascribed to a combination of local electromagnetic field enhancement because of the plasmon resonance of AgNPs and proper excitation of samples in resonance with the Q-band of NiTsPc.
Author	Costa, Ítalo A Paterno, Leonardo G Sales, Maria José A Soler, Maria A. G Pereira-da-Silva, Marcelo A Rivera, Luis Miguel R Moreira, Sanclayton G. C Maciel, Ayessa P
AuthorAffiliation	Instituto de Física de São Carlos, IFSC Centro Universitário Central PaulistaUNICEP Instituto de Física Universidade de São Paulo Universidade Federal do Pará Instituto de Ciências Exatas e Naturais (ICEN) Laboratório de Pesquisa em Polímeros e Nanomaterials, Instituto de Química
AuthorAffiliation_xml	– name: Centro Universitário Central PaulistaUNICEP – name: Instituto de Ciências Exatas e Naturais (ICEN) – name: Instituto de Física de São Carlos, IFSC – name: Universidade de São Paulo – name: Laboratório de Pesquisa em Polímeros e Nanomaterials, Instituto de Química – name: Universidade Federal do Pará – name: Instituto de Física
Author_xml	– sequence: 1 givenname: Ítalo A surname: Costa fullname: Costa, Ítalo A organization: Laboratório de Pesquisa em Polímeros e Nanomaterials, Instituto de Química – sequence: 2 givenname: Ayessa P surname: Maciel fullname: Maciel, Ayessa P organization: Laboratório de Pesquisa em Polímeros e Nanomaterials, Instituto de Química – sequence: 3 givenname: Maria José A surname: Sales fullname: Sales, Maria José A organization: Laboratório de Pesquisa em Polímeros e Nanomaterials, Instituto de Química – sequence: 4 givenname: Luis Miguel R surname: Rivera fullname: Rivera, Luis Miguel R organization: Instituto de Física – sequence: 5 givenname: Maria A. G surname: Soler fullname: Soler, Maria A. G organization: Instituto de Física – sequence: 6 givenname: Marcelo A surname: Pereira-da-Silva fullname: Pereira-da-Silva, Marcelo A organization: Centro Universitário Central PaulistaUNICEP – sequence: 7 givenname: Sanclayton G. C surname: Moreira fullname: Moreira, Sanclayton G. C organization: Universidade Federal do Pará – sequence: 8 givenname: Leonardo G orcidid: 0000-0001-7716-0318 surname: Paterno fullname: Paterno, Leonardo G email: lpaterno@unb.br organization: Laboratório de Pesquisa em Polímeros e Nanomaterials, Instituto de Química
BookMark	eNp1kElPwzAQhS0EEm3hztE_gBQvWZxjVbFUKosUOEeTxKGuEk-xnUP59aS04sZpnmbmPT19U3Ju0WpCbjibcyb4HdR-vt3V9VxVLGOKn5EJz6WIsjhJzv90nF2SqfdbxhLJuJyQr7cNBqwhQLcPpqbPOmywoS06GjaaFqYfugBW4-BpsbfjzhtPwTZ01fdYmc58QzBoKbZ08UlfwOIO3JjUaU_RBqQFdqahxVD54CBof0UuWui8vj7NGfl4uH9fPkXr18fVcrGOQCgWIohlqjWXaRpXlVaiifOGqVYyKas4UzxPOc8EZFwwgLxVMW-EUDIXQiStzCs5I-yYWzv03um23DnTg9uXnJUHZOWIrDwgK0_IRsvt0fJ7wcHZseD_7z--73L-
CitedBy_id	crossref_primary_10_1021_acs_analchem_2c03782 crossref_primary_10_1002_pssa_201900965 crossref_primary_10_2217_nnm_2023_0312 crossref_primary_10_1016_j_jallcom_2020_158189
Cites_doi	10.1016/j.jphotochem.2009.04.008 10.1021/jp2031576 10.1063/1.1674108 10.1021/nl9035109 10.1021/ja01539a017 10.1021/nl904286r 10.1016/j.colsurfa.2006.04.012 10.1021/am200480b 10.1039/f19827802677 10.1021/ja0395846 10.1016/0022-2852(61)90236-3 10.1016/j.apsusc.2011.03.036 10.1016/j.materresbull.2018.06.030 10.1016/j.trac.2014.05.003 10.1021/la0513353 10.1021/nn202294b 10.1111/j.1151-2916.2000.tb01566.x 10.1002/mame.200600264 10.1021/cr0500535 10.1021/jp066539m 10.1016/j.jphotochemrev.2014.09.001 10.1021/j100297a017 10.1021/jp013219o 10.1007/s11244-011-9666-1 10.1021/ja980350+ 10.1007/978-3-662-09109-8 10.1088/1361-6528/aa9238 10.1073/pnas.0811754106 10.1063/1.2196057 10.1021/ja00756a055 10.1021/cr100313v 10.1021/am500631f 10.1016/j.jphotochemrev.2008.11.002 10.1103/physrevb.71.184302 10.1007/s11581-017-2413-2 10.1021/la020078o 10.1088/0957-4484/10/4/305 10.1038/nnano.2007.451 10.1039/c0ce00215a 10.1016/j.jcis.2018.03.086 10.1021/nl9017918 10.1021/nn800251f 10.1016/j.apcatb.2014.05.035 10.1016/j.drudis.2014.11.014 10.1016/j.renene.2018.03.003
ContentType	Journal Article
DBID	AAYXX CITATION
DOI	10.1021/acs.jpcc.8b07081
DatabaseName	CrossRef
DatabaseTitle	CrossRef
DatabaseTitleList
DeliveryMethod	fulltext_linktorsrc
Discipline	Chemistry
EISSN	1932-7455
EndPage	24119
ExternalDocumentID	10_1021_acs_jpcc_8b07081 c012318214
GroupedDBID	.K2 53G 55A 5GY 5VS 7~N 85S 8RP AABXI ABFLS ABMVS ABPPZ ABUCX ACGFS ACNCT ACS AEESW AENEX AFEFF ALMA_UNASSIGNED_HOLDINGS AQSVZ BAANH CS3 D0L DU5 EBS ED ED~ EJD F5P GNL IH9 IHE JG JG~ K2 RNS ROL UI2 UKR VF5 VG9 VQA W1F 4.4 AAYXX ABJNI ABQRX ADHLV AHGAQ CITATION CUPRZ GGK
ID	FETCH-LOGICAL-a280t-a436ee13664bbe82d49d08f3033b4781961172a7120aa9f841d228392225f39b3
IEDL.DBID	ACS
ISSN	1932-7447
IngestDate	Fri Aug 23 01:44:07 EDT 2024 Thu Aug 27 13:42:05 EDT 2020
IsPeerReviewed	true
IsScholarly	true
Issue	42
Language	English
LinkModel	DirectLink
MergedId	FETCHMERGED-LOGICAL-a280t-a436ee13664bbe82d49d08f3033b4781961172a7120aa9f841d228392225f39b3
ORCID	0000-0001-7716-0318
PageCount	10
ParticipantIDs	crossref_primary_10_1021_acs_jpcc_8b07081 acs_journals_10_1021_acs_jpcc_8b07081
ProviderPackageCode	JG~ 55A AABXI GNL VF5 7~N VG9 W1F ACS AEESW AFEFF .K2 ABMVS ABUCX IH9 BAANH AQSVZ ED~ UI2
PublicationCentury	2000
PublicationDate	20181025 2018-10-25
PublicationDateYYYYMMDD	2018-10-25
PublicationDate_xml	– month: 10 year: 2018 text: 20181025 day: 25
PublicationDecade	2010
PublicationTitle	Journal of physical chemistry. C
PublicationTitleAlternate	J. Phys. Chem. C
PublicationYear	2018
Publisher	American Chemical Society
Publisher_xml	– name: American Chemical Society
References	ref9/cit9 ref6/cit6 ref36/cit36 ref3/cit3 ref27/cit27 ref18/cit18 Kreibig U. (ref2/cit2) 1995 ref11/cit11 ref25/cit25 ref16/cit16 ref29/cit29 ref32/cit32 ref23/cit23 ref39/cit39 ref14/cit14 ref8/cit8 ref5/cit5 ref31/cit31 ref43/cit43 ref34/cit34 ref37/cit37 ref28/cit28 ref40/cit40 ref20/cit20 ref17/cit17 ref10/cit10 ref26/cit26 ref35/cit35 ref19/cit19 ref21/cit21 ref12/cit12 ref15/cit15 ref42/cit42 ref46/cit46 ref41/cit41 ref22/cit22 ref13/cit13 ref33/cit33 ref4/cit4 ref30/cit30 ref1/cit1 ref24/cit24 ref38/cit38 ref44/cit44 Silverstein R. M. (ref45/cit45) 2005 ref7/cit7
References_xml	– ident: ref26/cit26 doi: 10.1016/j.jphotochem.2009.04.008 – ident: ref39/cit39 doi: 10.1021/jp2031576 – ident: ref34/cit34 doi: 10.1063/1.1674108 – ident: ref38/cit38 doi: 10.1021/nl9035109 – ident: ref27/cit27 doi: 10.1021/ja01539a017 – ident: ref32/cit32 doi: 10.1021/nl904286r – ident: ref8/cit8 doi: 10.1016/j.colsurfa.2006.04.012 – ident: ref17/cit17 doi: 10.1021/am200480b – ident: ref21/cit21 doi: 10.1039/f19827802677 – ident: ref16/cit16 doi: 10.1021/ja0395846 – ident: ref43/cit43 doi: 10.1016/0022-2852(61)90236-3 – ident: ref40/cit40 doi: 10.1016/j.apsusc.2011.03.036 – ident: ref10/cit10 doi: 10.1016/j.materresbull.2018.06.030 – ident: ref5/cit5 doi: 10.1016/j.trac.2014.05.003 – ident: ref7/cit7 doi: 10.1021/la0513353 – ident: ref25/cit25 doi: 10.1021/nn202294b – ident: ref9/cit9 doi: 10.1111/j.1151-2916.2000.tb01566.x – ident: ref41/cit41 doi: 10.1002/mame.200600264 – ident: ref19/cit19 doi: 10.1021/cr0500535 – ident: ref37/cit37 doi: 10.1021/jp066539m – ident: ref46/cit46 doi: 10.1016/j.jphotochemrev.2014.09.001 – ident: ref42/cit42 doi: 10.1021/j100297a017 – ident: ref6/cit6 doi: 10.1021/jp013219o – ident: ref22/cit22 doi: 10.1007/s11244-011-9666-1 – ident: ref30/cit30 doi: 10.1021/ja980350+ – volume-title: Optical Properties of Metal Clusters year: 1995 ident: ref2/cit2 doi: 10.1007/978-3-662-09109-8 contributor: fullname: Kreibig U. – ident: ref11/cit11 doi: 10.1088/1361-6528/aa9238 – ident: ref33/cit33 doi: 10.1073/pnas.0811754106 – ident: ref36/cit36 doi: 10.1063/1.2196057 – ident: ref20/cit20 doi: 10.1021/ja00756a055 – ident: ref4/cit4 doi: 10.1021/cr100313v – ident: ref23/cit23 doi: 10.1021/am500631f – ident: ref15/cit15 doi: 10.1016/j.jphotochemrev.2008.11.002 – ident: ref31/cit31 doi: 10.1103/physrevb.71.184302 – ident: ref14/cit14 doi: 10.1007/s11581-017-2413-2 – ident: ref44/cit44 doi: 10.1021/la020078o – ident: ref28/cit28 doi: 10.1088/0957-4484/10/4/305 – ident: ref29/cit29 doi: 10.1038/nnano.2007.451 – volume-title: Spectrometric Identification of Organic Compounds year: 2005 ident: ref45/cit45 contributor: fullname: Silverstein R. M. – ident: ref3/cit3 doi: 10.1039/c0ce00215a – ident: ref13/cit13 doi: 10.1016/j.jcis.2018.03.086 – ident: ref18/cit18 doi: 10.1021/nl9017918 – ident: ref35/cit35 doi: 10.1021/nn800251f – ident: ref24/cit24 doi: 10.1016/j.apcatb.2014.05.035 – ident: ref1/cit1 doi: 10.1016/j.drudis.2014.11.014 – ident: ref12/cit12 doi: 10.1016/j.renene.2018.03.003
SSID	ssj0053013
Score	2.351726
Snippet	A photocatalytic method based on layer-by-layer photocatalyst films made of titanium dioxide nanoparticles and graphene oxide, TiO2NPs/GO, is proposed for...
SourceID	crossref acs
SourceType	Aggregation Database Publisher
StartPage	24110
Title	Photocatalytic Method for the Simultaneous Synthesis and Immobilization of Ag Nanoparticles onto Solid Substrates
URI	http://dx.doi.org/10.1021/acs.jpcc.8b07081
Volume	122
hasFullText	1
inHoldings	1
isFullTextHit
isPrint
link	http://sdu.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwlV07T8MwELagDLDwRpSXPMDAkBI_4thjVajKAEIKSGyREztQhJJC2qH_nrOTShUCCaZIluVEd-e773IvhM4LQBXCyjzIjeIB1yoKJBE6yHQsuLWC2NgVJ4-S-P5ZXt8st8n5HsGn5Ernde9tkuc9mYF4uirrNQpPl77XHyQLrRuBoLImggyIkfO4DUn-dIIzRHm9ZIiWLMpw6z_fso02W9yI-w2jd9CKLXfR-mAxrm0PfTy8VtPK_42Zwx5850dDY8CkGDAeTsYudVCXFjx9nMxLWKvHNdalwbcgii5FtinIxFWB-y8YtC64023WHHZNDnBSvY8NdprGd7St99HT8OZxMAraeQqBpjKcBpozYS1hQvAss5IarkwoCzBiLHMVp0oQgDM6JjTUWhWSE-Oa4yjnEhZMZewAdcqqtIcIR4ZLBnyMdci4iKgUKnKudgHvsFzoLroAWqXtfahTH-qmJPWLQMC0JWAXXS6YkE6a9hq_7j3645nHaANQjW9aS6MT1Jl-zuwpWq3N7MyLzBeTWLzd
link.rule.ids	315,782,786,2769,27085,27933,27934,56747,56797
linkProvider	American Chemical Society
linkToHtml	http://sdu.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV07T8MwELagDGXhjShPDzAwBOrEceyxKkWtaCukFIktcmIHilBSSDv033N2EtEBJMRqWY51d_Z9l7v7jNBlCqiCaZ44iRLUoVL4DidMOrEMGNWaER2Y5uR-GIyf-V3P0OSQuhcGNlHASoVN4n-zC5BbM_Y2S5IbHoOVmmbrDZ8BFjZoqBvWl68P9uqViWQAjpQGVWbypxWMP0qKFX-04ljut_-xpR20VaFI3CnVvovWdLaHmt368bZ99PH4ms9z-29mCXPwyD4UjQGhYkB8OJyaQkKZaYj7cbjMYKyYFlhmCg_AME3BbNmeifMUd14w3MEQXFc1dNhQHuAwf58qbO4dy29bHKCn-96k23eq1xUc6fL23JHUY1oTjzEax5q7igrV5im4NC82_aeCEQA3MiBuW0qRckqUocoRJkBMPRF7h6iR5Zk-QthXlHug1UC2Pcp8lzPhm8A7hW9oymQLXYGsoup0FJFNfLsksoMgwKgSYAtd17qIZiXZxq9zj_-45gVq9iejYTQcjB9O0CbgHUtn6_qnqDH_XOgztF6oxbm1oi9apMVK
linkToPdf	http://sdu.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV07T8MwELagSMDCG1GeHmBgCMSx49hj1VK1AqpKAYktcmIHilBSSDv033POQ-oAEmK1LMe6O_u-y919RugyBVTBjUicREvmMCV9RxCunFgFnBnDiQlsc_IgDEYvondnaXL8phcGNlHASkWZxLeneqrTmmGA3Nrx92mS3IgYLNU2XK_5PJA25up0w-YC9sFmaZVMBvDIWFBnJ39awfqkpFjySUvOpb_9z23toK0aTeJOpf5dtGKyPbTRbR5x20ef47d8lpf_aBYwBz-WD0ZjQKoYkB8OJ7agUGUG4n8cLjIYKyYFVpnGQzBQWzhbtWniPMWdVwx3MQTZdS0dttQHOMw_Jhrb-6fkuS0O0HP_7qk7cOpXFhzlCXfmKEa5MYRyzuLYCE8zqV2Rgmujse1DlZwAyFEB8VylZCoY0ZYyR9pAMaUypoeoleWZOULY10xQ0G6gXMq47wkufRuAp_ANw7hqoyuQVVSfkiIqE-AeicpBEGBUC7CNrht9RNOKdOPXucd_XPMCrY97_ehhOLo_QZsAe0pWW88_Ra3Z19ycodVCz89LQ_oG9GbHzQ
openUrl	ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Photocatalytic+Method+for+the+Simultaneous+Synthesis+and+Immobilization+of+Ag+Nanoparticles+onto+Solid+Substrates&rft.jtitle=Journal+of+physical+chemistry.+C&rft.au=Costa%2C+I%CC%81talo+A&rft.au=Maciel%2C+Ayessa+P&rft.au=Sales%2C+Maria+Jose%CC%81+A&rft.au=Rivera%2C+Luis+Miguel+R&rft.date=2018-10-25&rft.pub=American+Chemical+Society&rft.issn=1932-7447&rft.eissn=1932-7455&rft.volume=122&rft.issue=42&rft.spage=24110&rft.epage=24119&rft_id=info:doi/10.1021%2Facs.jpcc.8b07081&rft.externalDocID=c012318214
thumbnail_l	http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=1932-7447&client=summon
thumbnail_m	http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=1932-7447&client=summon
thumbnail_s	http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=1932-7447&client=summon